《新建年产300吨5_溴-6-甲基脲嘧啶、300吨双二甲苯胺基甲胺项目废水处理设计方案》.doc

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1、、年产300吨5-溴-6-甲基脲嘧啶、300吨双二甲苯胺基甲胺项目废水处理设计方案 年产300吨5-溴-6-甲基脲嘧啶项目废水处理设计方案Opinions and suggestions on the partys mass line educational practiceAccording to the central and provincial, municipal unified deployment, according to municipal Party committee about carrying out the partys mass line educational

2、practice activity in the citys implementation opinions, the spirit of the partys mass line educational practice activities from 20* in January to 99 months, carried out at all levels of departments and directly affiliated institutions and grass-roots party organizations. According to my actual Count

3、y, the county to carry out the education practice put forward the following implementation opinions.First, the overall requirementsCounty county education practice to the eighteen Party of eight, the spirit of the the third Plenary Session of the 18th CPC Central Committee as the guidance, conscient

4、iously implement the spirit of general secretary Xi Jinping book series of important speech, earnestly implement the Central Committee really, opinions and advice , party implementing the guiding ideology of opinions to determine the objectives and requirements, step method, in accordance with the l

5、ook in the mirror, dress up, wash bath, cure treatment, the general requirements of for the people pragmatic honest people as the theme, in carrying forward the spirit of Zhuanglang Zhuang, improve their work style, service to the masses of the people, the foundation of consolidating grassroots, pro

6、mote transformation across efforts, to further implement the central eight regulations and The opposition party and government austerity waste regulations , double section provincial regulations, municipal provisions of the twelve plan and the implementation measures for on improving the work style

7、of close ties with the masses law, highlight style building, carry out the whole wind spirit, resolutely oppose formalism, bureaucracy, hedonism and wasteful extravagance to solve the problems, Party members and cadres of the style and the masses of people strong, the Ministry of Party members and c

8、adres to further improve their thinking and understanding, to further change the style of the wind, the masses to close, honest and pragmatic people honest image to further establish the foundation to further reinforce the basic level. Style of the building of the new results to promote the construc

9、tion of a powerful force of the county and the ecological culture of the county and county construction.In educational practice activities of the unit is mainly: the county and below county departments under the organs, enterprises and institutions directly under the township, street, and community,

10、 village, non-public economic organizations, social organizations and other grass-roots organizations. Agencies and branches, each single unit, follow the rules on internal institutions. Educational practice with step by step.To adhere to the county leadership, leadership and leading cadres to focus

11、 on outstanding catch to directly contact the service of the masses of law supervision departments and window units, service industry, educational practice, pay attention to grasp the heavy towns, streets and villages, community education activities and the masses of grassroots groups in close conta

12、ct to strengthen, and the majority of Party members, cadres and the mass line line Marx doctrine view of the masses and the partys education.Always speak seriously as a basic attitude, adhere to positive education, to carry out criticism and self criticism group, adhere to the pragmatic, more emphas

13、is on leadership, pay more attention to the layers of the demonstration, more focus on the four winds, solve the problem, pay more attention to open the door, the participation of the masses, pay more attention to the classification guidance. Orderly, pay more attention to the cooperation and cohesi

14、on driven, more strict requirements on injection, really supervision practice, ensure education practice is not empty is not empty is not partial, not as a mere formality.Two, the key point of the taskThe main task of the countys education practice is to seize against four wind this focus on central

15、ized solve outstanding problems asked County, township leadership and leading cadres of the four winds, the disadvantages of the style, scale behavior to a large scale investigation, overhaul, cleaning greatly. At the same time, respond to the concerns of the masses, safeguard the interests of the m

16、asses, pay attention to solve practical problems, solve the people around the unwholesome tendencies especially on eat, take the card, Yong lazy luxury, extravagance and waste fees, privileges and other issues, timely and effective, without any discount to solve, to improve the style of real impleme

17、ntation of the requirements of real to the grassroots, real let group Benefit the public.(a) focus on solving the four winds outstanding issuesThe central and provincial requirements, the county leadership and leading cadres of key performance concept is not correct, do not dare to play, to engage i

18、n image project, political project, a leadership guide, a set of ideas, orders and prohibitions, and a policy, there are countermeasures county. The units directly under the heavy focus on solving Yung lazy drag, buck passing skin, work is not implemented, the service is not active. The dynamic prob

19、lem of law enforcement and supervision departments and window units, service industry mainly solve the door hard, ugly face, something difficult, and arbitrary charges, fines, levies, and breach of privilege, chinakayao, not the problem of law. The township, street The collar of leading bodies and l

20、eading cadres to solve key does nottheir own conditions to develop the correct road, the maximum to avoid investment risk, gain profit.(three) vigorously promote the brand. To establish brand awareness, awareness of the use of brand, brand value, brand acquisition performance, enhance the competitiv

21、e strength. Concentrated manpower, careful planning, packaging and publicity of a number of unique, market influence and coverage of the brand, the implementation of key breakthroughs, to enhance the competitive strength, walking business road the competition of alienation and characteristics, the p

22、ursuit of stability and development of the market.(four) to promote the integration of resources. To further broaden their horizons, effective integration of resources within the group, the city resources, other industries and regional resources, mutual trust, mutual benefit, seeking win-win princip

23、le, in the framework of national policies and regulations, strict inspection and argumentation, legal consultation, examination and approval procedures, strict regulation of economic activities, attract injection the social investment to the industry group, to achieve leveraging the development, ens

24、ure that the value of state-owned assets.(five) to strengthen the construction management personnel. Strengthen the management of education and training of cadres and workers of the existing business, firmly establish the concept of the market, enhance the sense of crisis to adapt to market competit

25、ion, the sense of urgency, improve the ability to respond to market competition, improve management and operation of the market. At the same time, according to the need of industrial development, vigorously the introduction of high-quality management management personnel, and strive to build a high-

26、quality professional management team, hard work, and promote the entire workforce knowledge structure, age structure, structure optimization and upgrading ability, enhance core competitiveness, adapt to the need of market competition.(six) seriously study the policy for policy. Serious research abou

27、t social support the development of cultural undertakings in the country and the XX policy, especially the policy of industrial development, financial investment policy, financial policy and tax policy, and actively seek policy, projects and funds, enterprise and industry group mission to promote le

28、apfrog development. 13 目 录 一、概述1二、设计依据1三、废水处理工艺流程5四、废水处理构筑物设计说明及规格8五、各处理单元构筑物污染物去除分担率11六、构筑物规格一览表11七、动力设备一览表11八、运行费用12九、工程总造价12十、售后服务13十一、估计施工进度14一、 概述:*化工有限公司位于江苏省*海洋经济开发区内,是一家民营企业。为了满足市场需求,*公司决定新建年产300吨5-溴-6-甲基脲嘧啶、300吨双二甲苯胺基甲胺项目。受厂方的委托和提供的有关基础资料,在总结我所多年处理生产废水的经验基础上,针对该项目废水特征,提出如下设计方案,以供*化工有限公司及市环保

29、局审定。二、设计依据1、 设计依据1设计技术规范及相关标准本废水处理项目的设计,施工与安装严格执行国家的专业技术规范与标准,其主要规范与标准如下:污水综合排放标准 GB8978-1996室外排水设计规范 GBJ14-87水污染物排放标准 GB4426-89混凝土结构设计规范 GBJ10-89城市污水处理污水、污泥排放标准 CJ3025-93给水排水工程结构设计规范 GBJ69-84钢结构设计规范 GB17-88水工混凝土结构设计规范 SDJ20-78钢筋混凝土工程施工及验收规范 GBJ204-83机械设备安装工程施工及验收规范 TJ231-75现场设备、工业管道焊接工程施工及验收规范 GBJ2

30、36-82电力装置的继电保护和自动装置设计规范 GB50062-92电气装置施工及验收规范 GBJ232-82建筑给水排水设计规范 GBJ15-88工业与民用供配电系统设计规范 GB50052-92低压配电装置及线路设计规范 GB50054-922、 废水水质、水量废水水量: 综合废水 48吨/天(工艺废水2吨/天)废水水质: 项目名称产生工段编号类别产生量(t/a)污染物浓度(mg/L)5-溴-6-甲基脲嘧啶萃取W1工艺废水543COD13554苯2210甲醇11049NaCl17.9%其它生活设施W2生活废水2000COD400悬浮物220氨氮25总磷6厂区W3初期雨水150COD150悬

31、浮物200车间W4地面冲洗水650COD5003、 执行污水排放标准处理后的水质应达到江苏省*经济开发区污水处理厂接管标准,见下表:序号污染物标准1PH6-92COD 500mg/L3氨氮25mg/L4苯0.5mg/L5SS400mg/L6磷酸盐1.0mg/L7甲醇 20mg/L三、废水处理工艺流程1、 设计原则(1) 、应满足环境保护的各项规定,水经处理后达标排放。(2) 、废水治理工程具有适当的安全系数,各工艺参数的选择略有富余。(3) 、选择工艺成熟可靠,并要结合厂方的实际情况。(4) 、在保证处理效果的基础上,设计上尽可能采用符合厂方的实际情况的新工艺、新技术,以保证设计工艺的先进性,

32、并为以后发展留有余地。(5) 、处理系统要操作方便,运行安全可靠,经常性运行费用尽可能要低。2、 处理工艺的选择项目废水主要为工艺废水、生活污水、地面冲洗水、初期雨水。废水的特点为含盐量和有机物高,NaCl含量为17.9%,针对项目废水特点,我所对其废水采取分质处理,废水治理方案共分为二部分:一是高浓度含盐废水的前处理;二是综合废水处理。(1)高浓度含盐废水前处理 废水水质5-溴-6-甲基脲嘧啶工艺废水中萃取工序废水盐份高,其废水水质情况如下:工艺废水水质情况表污染物CODCR mg/l苯mg/l盐%二甲苯mg/l甲醇mg/l含 量13554221017.93.1711049处理能力项目对工艺

33、废水拟采用蒸发浓缩的处理方式,间歇操作运行,每天运行一次,处理量为2.0米m3/日,安装350千克/小时流量计,每天操作(含调节等预处理)10小时。处理工艺流程 工艺废水2.0m3/日中和调节池蒸发浓缩冷 却后续处理工序 冷凝水 废盐晶、有机残渣高浓度含盐废水处理工艺流程图工艺说明a. 中和调节池 由于工艺废水排放不稳定,先将废水引入调节池再用废水泵转至储液缸暂存,趁热用计量泵,经过换热器预热后送入蒸发器蒸发浓缩。b. 蒸发浓缩由于项目工艺废水中主要污染物为盐类和有机物,蒸发浓缩的基本原理是利用废水加热沸腾后,水和非挥发性的溶解物(盐类,大分子有机物)相分离,甲醇可汽提回收利用。通过蒸发浓缩除

34、盐而使废水得到净化,并提高其可生化性。工艺废水从旋流式薄膜蒸发器顶部的进口沿切线方向流进 ,由于速度很高,离心力很大,因而形成均匀的螺旋形薄膜,紧贴器壁流下,在内壁外层蒸汽夹套的加热下,液膜迅速沸腾汽化。析出的废盐晶和蒸发残渣由椎底排出,蒸发器的二、三次蒸汽通过换热器加热废水,从而节约蒸汽的消耗;液体进入调节池进行后续处理。从夹套中出来的蒸汽再经冷凝器冷却后进入中和调节池进行后续处理。c. 废晶盐、蒸馏残液处理项目工艺废水蒸馏产生的废晶盐和有机残液(主要含高沸点、难降解的大分子)有机物,均属危险废物,收集后密闭保管,送盐城宇新固体废物处置有限公司处置。(2)综合废水处理 设计处理能力经预处理的

35、工艺废水、生活污水、地面冲洗水及初期雨水合并后进行综合处理,其设计处理能力为48立米/日(不考虑蒸发析盐前后废水量的变化)。 综合废水处理工艺流程 见下工艺废水2.0m3/日 其它废水46m3/日调节(PH)池2冷 却蒸发浓缩调节池1 冷凝水 上清液 厌氧微电解塔 废盐晶、有机残渣 药剂二沉生物炭床絮凝反应器接触氧化塔斜板沉淀器 边 出水污泥干化场污泥浓缩池 污泥外运 工艺流程图四、 水处理构筑物设计说明及规格1.格栅车间排放的污水经过格栅、格网,可以截留大块污物,颗粒状物体等,以防止其后管道和设备堵塞。进水渠断面为400mm400mm,粗格栅的栅条间距为10mm,细格网网格间距为3mm,均采

36、用人工清渣。2.调节池2 该池主要将不同种类、不同浓度的废水集中到一个相应的水池中,通过机械搅拌使之充分混合从而使废水均质、衡量,减小对后续处理的冲击负荷,以达到稳定运行的目的,同时也可以使大颗粒的沉砂得到沉降并调节PH=3-5。 调节池有效容积约为240m3,停留时间为120小时。地下钢筋混凝土结构,环氧防腐。3. 厌氧微电解塔厌氧氧化通常分为水解、酸化、乙酸化和甲烷化四个步骤。芳香烃类等其它化合物对一般厌氧菌有一定的毒害作用,使生化菌的作用受到抑制,难以降解。但在微电解反应条件下,芳香烃类等其它化合物将被迅速分解为无毒性或毒性较小的小分子有机物,提高了废水的可生化性,同时去除了部分的COD

37、cr。水力停留时间为5 h,钢结构,环氧防腐。4絮凝反应器絮凝反应采用涡流反应工艺,具有停留时间充分、反应效果好;水力停留时间为1h,钢结构,环氧防腐。5. 斜板沉淀器斜板沉淀器的优点是停留时间短,沉淀效率高,占地省。设计流量为1m3/h。沉淀段表面负荷为1.0m3/m2h,沉淀时间为2.0h,超高200mm,上清液高度为700mm,沉淀区有效水深为900mm,缓冲层高度为700mm,污泥斗高度为1100mm,沉淀区加装PVC斜板,A3钢结构,环氧防腐。6. 接触氧化塔(PACT)接触氧化池采用鼓风机提供氧气,使微生物能利用污水中的有机污染物作为底料,进行正常的新陈代谢,从而降低污水中有机污染

38、物的浓度。在溶解氧和营养物都充足的情况下,微生物繁殖迅速,生物膜逐渐增厚,溶解氧和污水中的有机物凭借扩散作用,为微生物所利用,从而达到去除污染物的目的。接触氧化池表面呈长方形(内装填料含悬挂填料及生物炭填料),废水从池首端进入,在曝气和水力条件的推动下,混合液均衡地向前流动,并从池尾端流出。接触氧化池任何两个断面都存在有机基质的浓度梯度,因此存在着基质降解动力,BOD降解菌为优占菌,可避免污泥膨胀问题。曝气池采用钢结构,设计流量为24m3/T,有效容积为10m3,水力停留时间10h。保护层高为400mm,有效水深为3600mm,气水比为15:1,需风量为30m3/h。采用盘状曝系统曝气, A3

39、钢结构,环氧防腐。为保证处理效果接触氧化池分两格。7生物炭床反应器(二沉池合建) 为确保处理效果,对排放水进行生物炭床反应器处理,使废水经处理后能稳定达标排放。生物活性炭工艺是一种生化和物化相结合的污水处理工艺,其主要作用是去除水中溶解性的有机污染物,在无溶解氧的条件下,活性炭与污染物质之间属于单纯的吸附作用;在有溶解氧的条件下,微生物利用水中溶解氧得以在炭表面上生长繁殖,降解水中的有机物。由于生物炭工艺结合了生化再生过程,因此活性炭使用周期长,可达3-5年。尺寸为2000mm h2500m(与二沉池合建),A3钢结构,环氧防腐。8、干化进一步减小污泥体积,使污泥干化,最终外运。外型尺寸为45

40、00mm3500mm1000mm。五、 处理单元构筑物污染物去除分担率污染指标CODcr苯SS甲醇值(mg/l)去除率(%)值(mg/l)去除率(%)值(mg/l)去除率(%)值(mg/l)去除率(%)工艺废水13554-2210-11049-调节池22545-359-1650-1616-厌氧微电解22911035.990148510323.280絮凝沉淀13754021.54059460161.650接触氧化塔550602.1590356.44032.380生物炭床385300.4380-16.250六、 构筑物规格一览表序号构筑物单元规格(m)数量有效容积停留时间1格栅井4004001座2

41、调节池13000200025001座12m312d3调节池29000600028001座120m3120hr4污泥浓缩池3000200040001座20m35污泥干化池4000200010001座8m2七、 动力设备一览表序号名称 数量备注1污水泵2台1.1KW2污泥泵1台1.5KW3真空泵1台2.2KW4输液泵1台3KW5曝气风机2台1.5KW八、运行费用 运行费用包括电费及药剂费,不包括折旧费、人工费。1、 电费装机总容量约为14.9Kw,实际使用141.5Kw/d.以每度电按0.5元计,则处理每吨废水的电费为2.19元(人工费未计)。2、 药剂费、材料费投加药剂、材料费共计0.60元/吨

42、水。3、 蒸汽2.2m2 100元/m2 = 220元/24m3 蒸汽费约计9.17元/吨水。总计处理每吨水费用为:2.19+0.60+9.17 =11.96元(上下浮动30%)九、 工程总造价1、 直接费用A、土建构筑物投资概算表 单位:(万元)序号构筑物单元规格(m)数量有效容积停留时间1格栅井4004001座-2调节池13000200025001座12m312d3调节池29000600028001座120m3120hr4污泥浓缩池3000200040001座20m3-5污泥干化池4000200010001座8m2-6设备基础800050004001座-小计 捌万元整(8.00万元)B设备投资概算表 单位:(万元)序号构筑物规格(m)数量单价总价1粗格栅细格网栅条10mm3mm2座2提升泵1.1KW2台3三效蒸发器5.5m2配真空泵1套4厌氧微电解塔120045001套5絮凝反应器120045001套6斜板沉淀器1000200045001台7反应加药系统A

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