MarineLine784+MSDS.pdf

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1、MATERIAL SAFETY DATA SHEET MarineLine 784 Part A (Resin) Revision Number 1.5 Revision Date April 2, 2001 SECTION 1 PRODUCT / SUBSTANCE AND COMPANY IDENTIFICATION Product Name: MarineLine Product Number: 784 Manufacturer: Advanced Polymer Coatings, Ltd. Address: 951 Jaycox Rd. - Avon, Ohio 44011 U.S.

2、A. Phone Number: +01 440 / 937-6218 toll free 800-334-7193 Fax Number: +01 440 / 937-5046 toll free 800-615-0233 CHEMTREC: +01 730 / 527-3887 toll free 800-424-9300 C.A.S. Chemical Name: Polyglycidal Ether of Poly (4-Hydroxystyrene B) Synonyms: 4-Glycidal Ether Phenyl Methyl Carbinol Homopolymer Int

3、ended Use: See Technical Data Sheet. For Professional Use Only. Application Method: See Application Specifications. For Professional Use Only. Previous Revision Date: February 1, 2001 HMIS Health Rating 2 Flammability 2 Reactivity 0 SECTION 2 COMPOSITION / INFORMATION OF INGREDIENTS # Chemical Name

4、CAS Number % 1. Polyglycidyl Ether of PHS-N 267414-21-1 40.0 75.0 2. Quartz 14808-60-7 20.0 45.0 3. Xylene 1330-20-7 2.0 5.0 4. Toluene 108-88-3 1.0 4.0 5a. Titanium Dioxide (present in white or gray color only) 13463-67-7 100.00 oC Upper Explosion Limit (UEL) No Data Lower Explosion Limit (LEL) No

5、Data Autoignition Temperature No Data Fire Hazard Classification (OSHA/NFPA) Class IIIB Extinguishing Media Ignition will give rise to Class B fire. In case of large fire use: alcohol foam, water spray. In case of small fire use: carbon dioxide (CO2), dry chemical, dry sand or limestone. 24 HOUR EME

6、RGENCY NUMBER: 800-424-9300 (toll free within Continental U.S.) 703-527-3887 (outside Continental U.S. may be called collect) PRODUCT INFORMATION: 440-937-6218 800-334-7193 Page 10 of 10 MATERIAL SAFETY DATA SHEET MarineLine 784 Part B (Catalyst) Revision Number 1.5 Revision Date April 2, 2001 Speci

7、al Fire Fighting Procedures A face shield should be worn. Firefighters should wear butyl rubber boots, gloves, and body suit and a self-contained breathing apparatus. Retain expended liquids from fire fighting for later disposal. Water spray may be used to cool closed containers exposed to fire. Unu

8、sual Fire and Explosion Hazards May generate toxic or irritating combustion products. Contact of liquid with skin must be prevented. Sudden reaction and fire may result if product is mixed with an oxidizing agent. May generate carbon monoxide gas. May generate toxic nitrogen oxide gases. May generat

9、e ammonia gas. Personnel in vicinity and downwind should be evacuated. SECTION 6 ACCIDENTAL RELEASE MEASURES Containment Techniques (Removal of ignition sources, diking, etc.) Shut off or remove all ignition sources. Stop the leak, if possible. Reduce vapor spreading with a water spray. Construct a

10、dike to prevent spreading (includes molten liquids until they freeze). Ventilate the space involved. Clean-Up Procedures If necessary recovery is not feasible, admix with dry soil, sand or non-reactive absorbent and place in an appropriate chemical waste container. Transfer to containers by suction,

11、 preparatory for later disposal. Place in metal containers for recovery or disposal. Flush area with water spray. Clean-up personnel must be equipped with self-contained breathing apparatus and butyl rubber protective clothing. For large spills, recover spilled material with a vacuum truck. Other Em

12、ergency Advice Open enclosed areas to outside atmosphere. Wear protective clothing, boots, gloves, and eye protection. SECTION 7 HANDLING AND STORAGE Storage Keep away from acids, oxidizers, heat, flames, sparks. Handle containers carefully to prevent damage and spillage. Material should be kept in

13、original containers. Keep in cool, dry, ventilated storage and in closed container. Smoking, high heat and open flames should not be permitted in storage areas. Storage area to be adequately ventilated. Product may partially freeze with extended exposure to cold temperatures, resulting in crystalliz

14、ation, haziness or separation. If this occurs, product should be warmed to 100- 140F. (38-60C.) for one hour and stirred until clear. 24 HOUR EMERGENCY NUMBER: 800-424-9300 (toll free within Continental U.S.) 703-527-3887 (outside Continental U.S. may be called collect) PRODUCT INFORMATION: 440-937-

15、6218 800-334-7193 Page 11 of 11 MATERIAL SAFETY DATA SHEET MarineLine 784 Part B (Catalyst) Revision Number 1.5 Revision Date April 2, 2001 Handling Avoid contact with skin or eyes. Avoid breathing of vapors. Handle in well-ventilated workspace. Use personal protection as shown in Section 8. When ha

16、ndling, do not eat, drink or smoke. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering Controls General Local Exhaust recommended. Eye Protection Full face shield with goggles underneath. Hand Protection Neoprene rubber gloves. Impermeable gloves. Cuffed butyl rubber gloves. Nitrile rubbe

17、r gloves. Respiratory Protection Gas and vapor removing, air purifying respirator (cartridge) Protective Clothing Impervious clothing. Slicker suit. Rubber boots. Full rubber suit (rain gear). Butyl or latex protective clothing. Work and Hygienic Controls Provide readily accessible eye wash stations

18、 and safety showers. Wash at the end of each workshift and before eating, smoking, or using the toilet. Promptly remove clothing that becomes contaminated. Discard contaminated leather articles, which may be saturated or unable to be cleaned. SECTION 9 TYPICAL PHYSICAL AND CHEMICAL PROPERTIES Physic

19、al Form: Mobile Liquid Color: Straw Yellow Odor: Amoniacal, Irritating pH Alkaline Vapor Pressure (mm Hg at 21 oC (70 oF) No Data Vapor Density (Air = 1) No Data Boiling Point 315.00C. ( 608F.) Melting Point No Data Solubility in Water 0.00% Specific Gravity (H20 = 1.0) 0.96 Molecular Weight 210 24

20、HOUR EMERGENCY NUMBER: 800-424-9300 (toll free within Continental U.S.) 703-527-3887 (outside Continental U.S. may be called collect) PRODUCT INFORMATION: 440-937-6218 800-334-7193 Page 12 of 12 MATERIAL SAFETY DATA SHEET MarineLine 784 Part B (Catalyst) Revision Number 1.5 Revision Date April 2, 20

21、01 SECTION 10 STABILITY AND REACTIVITY Chemical Stability Stable Conditions to Avoid (if unstable) Not Applicable Incompatibility (Materials to Avoid) Mineral acids, (i.e. sulfuric, phosphoric, etc.) Organic acids (i.e. acetic, citric, ets.) Oxidizing agents (i.e. perchlorates, nitrates, etc.). Sodi

22、um or calcium hypochlorite. Product slowly corrodes copper, aluminum, zinc, and galvanized surfaces. Reaction with peroxides may result in violent decomposition of peroxide possibly creating an explosion. A reaction accompanied by large heat release occurs when the product is mixed with acids. Heat

23、generated may be sufficient to cause vigorous boiling creating a hazard due to splashing or splattering of hot material. Hazardous Decomposition Products (from burning, heating or reaction with other materials) Carbon monoxide in a fire. Carbon dioxide in a fire. Ammonia when heated. Nitrogen oxides

24、 in a fire. Irritating and toxic fumes at elevated temperatures. Nitric acid in a fire. Nitrogen oxide can react with water vapors to form corrosive nitric acid (TLV = 2 ppm). Hazardous Polymerization Will not occur SECTION 11 TOXICOLOGICAL PROPERTIES Acute Oral Toxicity (LD 50, Rat) 625.00 mg/kg (E

25、stimate) Acute Dermal Toxicity (LD 50, Rabbit) 2,110.00 mg/kg Acute Inhalation Toxicity (LC 50, Rat) 10.00 mg/l/hr (No deaths) (Estimate) Other Acute Effects No Data Irritation Effects Data Corrosive to the skin of a rabbit. Chronic/Subchronic Data Sensitization has occurred in laboratory animals after repeated exposures. 24 HOUR EMERGENCY NUMBER: 800-424-9300 (toll free within Continental U.S.) 703-527-3887 (outside Continental U.S. may be called collect) PRODUCT INFORMATION: 440-937-6218 800-334-7193 Page 13 of 13

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