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1、BRITISH STANDARD BS 4267-4: 1987 Ammonium nitrate Part 4: Method for determination of sulphated ash NOTEIt is recommended that this Part of BS 4267 be read in conjunction with the information in the “General introduction”, published separately as BS 4267-0. WARNING. Ammonium nitrate is a strong oxid
2、izing agent. If necessary, break the test sample up by crushing rather than grinding. UDC 661.525:546.39175: 543 Licensed Copy: sheffieldun sheffieldun, na, Fri Dec 01 08:19:16 GMT+00:00 2006, Uncontrolled Copy, (c) BSI BS 4267-4:1987 This British Standard, having been prepared under the direction o
3、f the Chemicals Standards Committee, was published under the authority of the Board of BSI and comes into effect on 30 September 1987 BSI 10-1999 The Committees responsible for this British Standard are shown in Part 0. The following BSI references relate to the work on this standard: Committee refe
4、rence CIC/21 Draft for comment 84/54870 DC ISBN 0 580 16117 X Foreword This Part of BS 4267 has been prepared under the direction of the Chemicals Standards Committee. It supersedes clause 5 of BS 4267:1968, to which it is technically equivalent and which has been deleted by amendment. This standard
5、 describes a method of test only, and should not be used or quoted as a specification defining limits of purity. Reference to this Part should indicate that the method of test used is in accordance with BS 4267-4:1987. A British Standard does not purport to include all the necessary provisions of a
6、contract. Users of British Standards are responsible for their correct application. Compliance with a British Standard does not of itself confer immunity from legal obligations. Summary of pages This document comprises a front cover, an inside front cover, pages i and ii, page 1 and a back cover. Th
7、is standard has been updated (see copyright date) and may have had amendments incorporated. This will be indicated in the amendment table on the inside front cover. Amendments issued since publication Amd. No.Date of issueComments Licensed Copy: sheffieldun sheffieldun, na, Fri Dec 01 08:19:16 GMT+0
8、0:00 2006, Uncontrolled Copy, (c) BSI BS 4267-4:1987 BSI 10-1999i Contents Page ForewordInside front cover 1Scope1 2Principle1 3Reagent1 4Apparatus1 5Procedure1 6Expression of results1 7Test report1 Licensed Copy: sheffieldun sheffieldun, na, Fri Dec 01 08:19:16 GMT+00:00 2006, Uncontrolled Copy, (c
9、) BSI ii blank Licensed Copy: sheffieldun sheffieldun, na, Fri Dec 01 08:19:16 GMT+00:00 2006, Uncontrolled Copy, (c) BSI BS 4267-4:1987 BSI 10-19991 1 Scope This Part of BS 4267 describes a gravimetric method for determination of the sulphated ash of ammonium nitrate for industrial use. The method
10、is applicable to products with a sulphated ash of not less than 0.1 % (m/m). 2 Principle A test portion is volatilized at about 225 C and then heated with sulphuric acid. The residue is then heated at about 850 C to constant mass. 3 Reagent 3.1 Sulphuric acid, concentrated, = 1.84 g/mL, analytical g
11、rade. 4 Apparatus 4.1 Ordinary laboratory apparatus 4.2 Platinum dish, about 75 mm in diameter. 4.3 Muffle furnace, capable of being maintained at 850 50 C. 5 Procedure 5.1 Test portion Weigh, to the nearest 0.1 g, about 100 g of the test sample. 5.2 Determination Heat the empty platinum dish (4.2)
12、in a muffle furnace at 850 50 C. Cool the dish in a desiccator and weigh to the nearest 0.1 mg. Repeat this process until successive weighings do not differ by more than 1 mg. Gradually introduce the test portion (5.1), not more than 5 g at a time, into the weighed platinum dish while heating the di
13、sh on a hotplate at approximately 200 C to 250 C in a fume cupboard. After each addition, wait until volatilization is completed. WARNING. If the ammonium nitrate is heated too rapidly, a violent decomposition may result. When all the ammonium nitrate has been volatilized, cool the dish and its cont
14、ents and then add a few drops of the sulphuric acid (3.1). Heat the dish on a hotplate until no further fumes are evolved, transfer the dish to the muffle furnace (4.3) and ignite the residue at 850 50 C. Cool the dish and its contents in a desiccator and weigh to the nearest 0.1 mg. Repeat the proc
15、ess of ignition, cooling and weighing until successive weighings do not differ by more than 1 mg. 6 Expression of results The sulphated ash, expressed as a percentage by mass, is given by the following expression: where 7 Test report The test report shall include the following information: a) an ide
16、ntification of the sample; b) a reference to this British Standard, i.e. BS 4267-4:1987; c) the results expressed in accordance with clause 6; d) any unusual features noted during the determination; e) any operation not included in this Part of BS 4267 or regarded as optional. M1is the mass of the f
17、inal residue (in g); M0is the mass of the test portion (5.1) (in g). 100M1 M0 - Licensed Copy: sheffieldun sheffieldun, na, Fri Dec 01 08:19:16 GMT+00:00 2006, Uncontrolled Copy, (c) BSI BS 4267-4: 1987 BSI 389 Chiswick High Road London W4 4AL BSI British Standards Institution BSI is the independent
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26、s. If these details are to be used for any other purpose than implementation then the prior written permission of BSI must be obtained. If permission is granted, the terms may include royalty payments or a licensing agreement. Details and advice can be obtained from the Copyright Manager. Tel: 020 8996 7070. Licensed Copy: sheffieldun sheffieldun, na, Fri Dec 01 08:19:16 GMT+00:00 2006, Uncontrolled Copy, (c) BSI