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1、 Reference number ISO 3063:2004(E) ISO 2004 INTERNATIONAL STANDARD ISO 3063 Second edition 2004-11-15 Oil of ylang-ylang Cananga odorata (Lam.) Hook. f. et Thomson forma genuina Huile essentielle dylang-ylang Cananga odorata (Lam.) Hook. f. et Thomson forma genuina Copyright International Organizati
2、on for Standardization Provided by IHS under license with ISO Licensee=NASA Technical Standards 1/9972545001 Not for Resale, 04/20/2007 03:52:49 MDTNo reproduction or networking permitted without license from IHS -,-,- ISO 3063:2004(E) PDF disclaimer This PDF file may contain embedded typefaces. In
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6、his publication may be reproduced or utilized in any form or by any means, electronic or mechanical, including photocopying and microfilm, without permission in writing from either ISO at the address below or ISOs member body in the country of the requester. ISO copyright office Case postale 56 CH-1
7、211 Geneva 20 Tel. + 41 22 749 01 11 Fax + 41 22 749 09 47 E-mail copyrightiso.org Web www.iso.org Published in Switzerland ii ISO 2004 All rights reserved Copyright International Organization for Standardization Provided by IHS under license with ISO Licensee=NASA Technical Standards 1/9972545001 N
8、ot for Resale, 04/20/2007 03:52:49 MDTNo reproduction or networking permitted without license from IHS -,-,- ISO 3063:2004(E) ISO 2004 All rights reserved iii Contents Page Forewordiv 1 Scope1 2 Normative references .1 3 Terms and definitions.1 4 Requirements 1 4.1 Appearance1 4.2 Colour.1 4.3 Odour
9、1 4.4 Physical and chemical requirements1 4.5 Chromatographic profile1 4.6 Flashpoint2 5 Sampling2 6 Test methods.2 6.1 Relative density at 20 C 20 20 d2 6.2 Refractive index at 20 C2 6.3 Optical rotation at 20 C .2 6.4 Acid value 2 6.5 Ester value.2 6.6 Chromatographic profile2 7 Packaging, labelli
10、ng, marking and storage2 Annex A (informative) Typical chromatograms of the analysis by gas chromatography of oil of ylang-ylang Cananga odorata (Lam.) Hook. f. et Thomson forma genuina.6 Annex B (informative) Flashpoint .11 Bibliography .12 Copyright International Organization for Standardization P
11、rovided by IHS under license with ISO Licensee=NASA Technical Standards 1/9972545001 Not for Resale, 04/20/2007 03:52:49 MDTNo reproduction or networking permitted without license from IHS -,-,- ISO 3063:2004(E) iv ISO 2004 All rights reserved Foreword ISO (the International Organization for Standar
12、dization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to
13、 be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. International Stan
14、dards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2. The main task of technical committees is to prepare International Standards. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an Int
15、ernational Standard requires approval by at least 75 % of the member bodies casting a vote. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. ISO 3063
16、was prepared by Technical Committee ISO/TC 54, Essential oils. This second edition cancels and replaces the first edition (ISO 3063:1983), which has been technically revised. Copyright International Organization for Standardization Provided by IHS under license with ISO Licensee=NASA Technical Stand
17、ards 1/9972545001 Not for Resale, 04/20/2007 03:52:49 MDTNo reproduction or networking permitted without license from IHS -,-,- INTERNATIONAL STANDARD ISO 3063:2004(E) ISO 2004 All rights reserved 1 Oil of ylang-ylang Cananga odorata (Lam.) Hook. f. et Thomson forma genuina 1 Scope This Internationa
18、l Standard specifies certain characteristics of the oil of ylang-ylang Cananga odorata (Lam.) Hook. f. et Thomson forma genuina from Madagascar, Mayotte and Comores, in order to facilitate assessment of its quality. 2 Normative references The following referenced documents are indispensa- ble for th
19、e application of this document. For dated references, only the edition cited applies. For un- dated references, the latest edition of the referenced document (including any amendments) applies. ISO/TR 210, Essential oils General rules for packaging, conditioning and storage ISO/TR 211, Essential oil
20、s General rules for labelling and marking of containers ISO 212, Essential oils Sampling ISO 279, Essential oils Determination of relative density at 20 C Reference method ISO 280, Essential oils Determination of refrac- tive index ISO 592, Essential oils Determination of optical rotation ISO 709, E
21、ssential oils Determination of ester value ISO 1242, Essential oils Determination of acid value ISO 11024-1, Essential oils General guidance on chromatographic profiles Part 1: Preparation of chromatographic profiles for presentation in stan- dards ISO 11024-2, Essential oils General guidance on chr
22、omatographic profiles Part 2: Utilization of chromatographic profiles of samples of essential oils 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1 oil of ylang-ylang essential oil obtained by steam distillation of the fresh flowers of Cananga
23、 odorata (Lam.) Hook. f. et Thomson forma genuina, of the Annonaceae family, growing mainly in Madagascar, Mayotte and Co- mores NOTE 1 This volatile product is not generally collected as a whole oil, but in five successive fractions during the course of distillation. These five fractions, known res
24、pec- tively as “Extra super”, “Extra”, “First”, “Second” and “Third”, are the oils usually found in the trade. NOTE 2 For information on the CAS number, see ISO/TR 21092. 4 Requirements 4.1 Appearance Liquid. 4.2 Colour Pale yellow to dark yellow. 4.3 Odour Characteristic, floral and recalling jasmi
25、ne. 4.4 Physical and chemical requirements See Table 1. 4.5 Chromatographic profile Analysis of the essential oil shall be carried out by gas chromatography. In the chromatogram obtained, the representative and characteristic components shown in Table 2 shall be identified. The proportions Copyright
26、 International Organization for Standardization Provided by IHS under license with ISO Licensee=NASA Technical Standards 1/9972545001 Not for Resale, 04/20/2007 03:52:49 MDTNo reproduction or networking permitted without license from IHS -,-,- ISO 3063:2004(E) 2 ISO 2004 All rights reserved of these
27、 components, indicated by the integrator, shall be as shown in Table 2. This constitutes the chromatographic profile of the essential oil. 4.6 Flashpoint Information on the flashpoint is given in Annex B. 5 Sampling See ISO 212. Minimum volume of test sample: 25 ml NOTE This volume allows each of th
28、e tests specified in this International Standard to be carried out at least once. 6 Test methods 6.1 Relative density at 20 C 20 20 d See ISO 279. 6.2 Refractive index at 20 C See ISO 280. 6.3 Optical rotation at 20 C See ISO 592. 6.4 Acid value See ISO 1242. 6.5 Ester value See ISO 709. 6.6 Chromat
29、ographic profile See ISO 11024-1 and ISO 11024-2. 7 Packaging, labelling, marking and storage See ISO/TR 210 and ISO/TR 211. Copyright International Organization for Standardization Provided by IHS under license with ISO Licensee=NASA Technical Standards 1/9972545001 Not for Resale, 04/20/2007 03:52
30、:49 MDTNo reproduction or networking permitted without license from IHS -,-,- ISO 3063:2004(E) ISO 2004 All rights reserved 3 Table 1 Physical and chemical requirements Fractions Extra super Extra First Second Third Characteristics Comores and Mayotte Comores and Mayotte Mada- gascar Comores and May
31、otte Mada- gascar Comores and Mayotte Mada- gascar Comores and Mayotte Mada- gascar Relative density at 20 C 20 20 d Min. 0,970 0,955 0,950 0,938 0,933 0,925 0,922 0,906 0,906 Max. 0,990 0,976 0,965 0,960 0,949 0,945 0,942 0,925 0,925 Refractive index at 20 C Min. 1,497 1,498 1,493 1,501 1,495 1,502
32、 1,496 1,503 1,502 Max. 1,505 1,506 1,509 1,509 1,510 1,511 1,511 1,513 1,513 Optical rotation at 20 C Min. 33 40 42 46 46 60 58 72 70 Max. 12,5 20 20 25 24 35 30 45 45 Acid value 2 2 2 2 2 2 2 2 2 Ester value Min. 160 140 125 100 90 75 65 45 40 Max. 200 185 160 160 125 115 95 75 70 Copyright Intern
33、ational Organization for Standardization Provided by IHS under license with ISO Licensee=NASA Technical Standards 1/9972545001 Not for Resale, 04/20/2007 03:52:49 MDTNo reproduction or networking permitted without license from IHS -,-,- ISO 3063:2004(E) 4 ISO 2004 All rights reserved Table 2 Chromat
34、ographic profile Fractions Extra super Extra First Second Third Component Comores and Mayotte Comores and Mayotte Mada- gascar Comores and Mayotte Mada- gascar Comores and Mayotte Mada- gascar Comores and Mayotte Mada- gascar Prenyl acetate Min. 1,5 1,0 0,6 0,3 0,2 0,2 0,1 0,1 traces Max. 3,2 2,3 2,
35、2 1,8 1,0 0,9 0,5 0,2 0,2 p-Cresyl methyl ether Min. 7,0 5,0 7,0 3,0 5,0 2,0 1,0 0,1 0,1 Max. 13,0 13,0 16,0 8,5 10,0 5,0 4,6 1,0 1,4 Methyl benzoate Min. 4,5 4,0 4,5 1,5 3,0 1,0 1,0 0,1 0,1 Max. 8,0 6,5 9,0 5,5 5,0 3,5 3,0 0,8 0,9 Linalool Min. 8,0 7,0 15,0 3,0 12,0 2,0 4,0 0,1 0,6 Max. 13,0 12,0 2
36、4,0 10,0 19,0 6,0 9,5 2,0 4,0 Benzyl acetate Min. 14,0 11,0 5,5 6,0 2,8 4,0 0,5 0,5 0,1 Max. 20,0 17,5 14,0 14,0 10,0 8,8 5,0 3,0 2,2 Geraniol Min. 0,1 0,1 1,3 0,1 1,6 0,1 0,7 traces 0,2 Max. 0,7 0,5 3,0 0,3 2,6 0,3 2,4 0,1 0,8 Geranyl acetate Min. 2,0 2,5 7,0 2,0 8,0 1,7 5,6 0,4 1,0 Max. 6,0 6,0 14
37、,0 5,0 15,0 6,0 12,0 3,0 6,6 E-Cinnamyl acetate Min. 4,0 3,0 0,5 2,2 0,5 2,0 0,4 0,5 0,1 Max. 6,0 6,5 3,0 5,0 2,0 4,8 2,2 2,5 2,0 -Caryophyllene Min. 2,0 2,5 2,5 4,0 5,5 4,8 10,0 5,0 12,0 Max. 6,0 8,0 8,5 10,0 12,0 14,0 17,0 15,0 19,0 D-Germacrene Min. 9,0 14,0 5,0 10,0 9,5 16,0 13,0 20,0 15,0 Max.
38、15,0 20,0 15,0 24,0 18,0 28,0 28,0 35,0 34,0 (E,E)- -Farnesene Min. 2,0 6,5 1,0 7,0 3,0 14,0 5,0 12,0 9,0 Max. 6,0 15,0 5,0 18,0 8,0 21,0 11,5 29,0 25,0 Copyright International Organization for Standardization Provided by IHS under license with ISO Licensee=NASA Technical Standards 1/9972545001 Not
39、for Resale, 04/20/2007 03:52:49 MDTNo reproduction or networking permitted without license from IHS -,-,- ISO 3063:2004(E) ISO 2004 All rights reserved 5 Table 2 (continued) Fractions Extra super Extra First Second Third Component Comores and Mayotte Comores and Mayotte Mada- gascar Comores and Mayo
40、tte Mada- gascar Comores and Mayotte Mada- gascar Comores and Mayotte Mada- gascar (E,E)-Farnesol Min. 0,8 0,8 0,5 0,8 0,1 0,8 1,2 0,8 1,2 Max. 1,5 1,6 3,0 2,0 2,5 3,0 3,5 3,0 4,0 Benzyl benzoate Min. 3,0 4,0 3,5 4,2 4,5 4,5 6,0 4,0 4,8 Max. 6,0 6,0 8,0 9,2 8,0 7,8 10,0 8,0 8,5 (E,E)- Farnesyl aceta
41、te Min. 1,0 1,0 0,5 1,0 1,0 1,0 1,2 1,5 1,7 Max. 3,0 3,0 3,0 4,0 2,0 3,5 3,5 5,0 5,0 Benzyl salicylate Min. 1,5 2,0 1,2 2,0 1,6 2,0 1,8 2,5 2,0 Max. 3,5 3,8 4,0 4,0 4,0 4,0 4,0 4,8 5,0 Copyright International Organization for Standardization Provided by IHS under license with ISO Licensee=NASA Techn
42、ical Standards 1/9972545001 Not for Resale, 04/20/2007 03:52:49 MDTNo reproduction or networking permitted without license from IHS -,-,- ISO 3063:2004(E) 6 ISO 2004 All rights reserved Annex A (informative) Typical chromatograms of the analysis by gas chromatography of oil of ylang-ylang Cananga od
43、orata (Lam.) Hook. f. et Thomson forma genuina Peak identification Operating conditions 1 Prenyl acetate 9 -Caryophyllene 2 p-Cresyl methyl ether 10 D-Germacrene 3 Methyl benzoate 11 (E,E)-Farnesene 4 Linalool 12 (E,E)-Farnesol 5 Benzyl acetate 13 Benzyl benzoate 6 Geraniol 14 (E,E)-Farnesyl acetate
44、 7 Geranyl acetate 15 Benzyl salicylate 8 E-Cinnamyl acetate Column: silica capillary, length 20 m, internal diameter 0,1 mm Stationary phase: methyl siloxane Film thickness: 0,40 m Oven temperature: isothermal at 80 C for 2 min, then tempera- ture programming from 80 C to 170 C at a rate of 4 C/min
45、, and from 170 C to 305 C at a rate of 15 C/min, and isothermal at 305 C for 2 min Injector temperature: 260 C Detector temperature: 300 C Detector: flame ionization type Carrier gas: hydrogen Volume injected: 0,2 l Carrier gas flow rate: 0,6 ml/min Split ratio: 1/120 Figure A.1 Typical chromatogram
46、 of oil of ylang-ylang Extra Comores taken on an apolar column Copyright International Organization for Standardization Provided by IHS under license with ISO Licensee=NASA Technical Standards 1/9972545001 Not for Resale, 04/20/2007 03:52:49 MDTNo reproduction or networking permitted without license
47、 from IHS -,-,- ISO 3063:2004(E) ISO 2004 All rights reserved 7 Peak identification Operating conditions 1 Prenyl acetate 9 -Caryophyllene 2 p-Cresyl methyl ether 10 D-Germacrene 3 Methyl benzoate 11 (E,E)-Farnesene 4 Linalool 12 (E,E)-Farnesol 5 Benzyl acetate 13 Benzyl benzoate 6 Geraniol 14 (E,E)-Farnesyl acetate 7 Geranyl acetate 15 Benzyl salicylate 8 E-Cinnamyl acetate Column: silica capillary, length 20 m, internal diameter 0,1 mm Stationary phase: methyl siloxane Film thickness: 0,4