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1、高硫含量对柴油使用性能的影响2008?1?B?H33?H1?u?O?2LUBRICATIONENGINEERINGJan12008Vol133No11?s?p?u:2007-07-10S?:?,E2mail:huzexiang6311(6zn),?,?C?B,?n?u,?.?O?L?11S?Y?2S?3S?S?L3(1.?v?92323?uS?m?266042;2.?v?O?C?S?400016;3.?O?c?U?n?jS?l?100072)?:?.?e?S2?W?K?n?T?A?;?.?)?S0?O,?;?5?o?2?0?),?K?)?.?,?u?E?,?a?K?S0?G?K?.?;?T?S
2、0?f?:?;?o?;?;?;?5?L?:TH11711S?f?U?2:AS?o?:0254-0150(2008)1-117-5TheInfluenceofSulfideonthePerformanceofDieselFuelsWangHongmei1S?ChenGuoxu2S?HuZexiang3S?WangKun3(1.Unit92323ofPLA,QingdaoShandong266042,China;2.TheLogisticalEngineeringInstitute,Chongqing400016,China;3.AcademyofNavalLogisticalTechnology
3、andEquipment,Beijing100072,China)Abstract:Theinfluenceofsulfideontheperformanceofdieselfuelswasstudiedbysimulationtestandenginetest.Theresultsshowthatburningresultantofhighcontentsulfidedieselfuelshasmorestrongacidicsulfide,whichinduceshardysediment(carbonization)inpiston/cylinderandcauseenginewear.
4、So,itisnotsuitableforourengineburningdieselfuelsofhighcontentsulfide.Keywords:dieselfuels;sulfide;sediment(carbonization);erode;wearS?G?.?1?,?;?U?U?w?N?o?X?012%1,?A?o?R?(?S?M?K?.?L?)?;?U?U?w?N?o?X?115%2?,?G?U?S0?C?5?4?d?,?o?;?,?.?)?R?;?G?K?;?c?W?4?.?o?Z?s?.?,?(?.?q?,?c?q?n?4?S0?5?;?o?L?K2?)?:?Q?)?o?
5、Q?)?o?S0?L?5?o?.?Q?N?L?M?A?u?o3S0?W?S2?R?L?5?o?GC2MS?L?1?2?j?KS0?L?,?W?R?L?5?o?Q?;?K46991998?g/mL,?5?9?9?;?K39971818?g/mL,?Q?;?85%?IS0?B?1S2?2?o?2?L?8?n?C?,?5?o?9?A?9?K?Q,?A?9?O?9?)?K3xs7S0?Z?L?L?5?o?L?8?,?H?3?R?9?9?.?3xs7?s?e?,?n?;?.?)?(?K)?S0?S?W?L?5?o?L?8(G2MS)FS?Dfff?81com:1971Cig1istributionoor
6、ganicsulideindistilledraction2S?W?R?L?5?o?L?8(GC2MS)Fig2S?Distributionoforganicsulfideindistilledfraction1S?111S?;?)?s?U?;?010(?F)S2016%S2018%S2110%S2112%?,?RGB/T5096291?M?4,?8?;?)S0?A?,?8?S?;?l?5,?K?)?,?,?.?I?8?;?K?)S0112S?K?Z?135D2?(SH/T0261294)5?135C2?(SH/T0075291)6,?.YS1135?W?K?I?,?8?T?A?;?K?.?)
7、?,?Q?L?C:(1)?Q?L:?1?4?.?Q?,?.100h?O,?3?)?L,?Q?Q?S0(2)?L?:?R?L?F?O?Q?,?XPS?L?,?8?/?z?E?o?2S0(3)?n?K?:?.?F?YS1135?W?K?A?,?K?n?n?V?Z?c?L?;?R?T?A?.?K?,?e?n?,?8?.?T?A?;?S02S?O?L?211S?;?)?;?)?3S0?3S?T?A?;?F?M?Fig3S?Coppercorrosiontestresultsofdieseloilswithdifferentsulfurcontent?4S?T?A?;?K?M?Fig4S?Copperc
8、orrosiontestresultsofdieselengineoilswithdifferentsulfurcontentS?3?4?,?RGB/T5096291?8?,?5?o?K?)?S0?;?K?)?4S0111,?.?.?C,?R1352C2?o1352D2?100h?,?O,?1?Q?3?)?L,?Q?Q?,?S0811?O?2?H33?82222111S?T?A?;?O?Q?3?)?LTable1S?Pistondetergencymarkondieselafterbenchtest?K?.?(?)?;?Q?3?)?L/?L?Q?e?K?8?1352C2?T?;?102?Q?;
9、?014%190?QCastrolCC?1352C2?T?;?169?Q?;?014%252?Q?;?014%209?QCD?(Myrina)1352D2?;?014%243?Q?;?014%210?QCD?(?-?.?K?)352D2?;?011%1)315?QCD?(?-?.?K?)1352D2?;?014%266?QCD?(?-?.?K?)1352D2?;?018%197?:1)?K?n?R?,?L?q?S0?1?,?.?A?C,?K?Q?3?)?L?T?,?Q?Q?C?)?T?F,?;?c?;S018%?,?Q?L?197?L,?K?O?Q?H?(?9?)?,?T?Q?,?.?O?CS
10、0?O,?5?;?K?Q?I?R?)?,?)?.?R?S021212S?L?2S?2?;?u?E?/?z?L?;?S?S?Table2S?RelativecontentofelementsdetectedincarbondepositproducedbytwodieselwithdifferentsulfurcontentpercentC1sO1sP2pS2p(?)811971612701411134(?)791171812201851176S?L?;?K011%?018%?O,?L?Q?XPS?L?,?L?5S2?6?j?KS0?2?5?/?z(S,P,O,C)?L?;?L?,?S0?5?o
11、?2?;?)?N,?S0?5S?;?011%?O?Q?XPS?L?S?Fig5S?XPSanalysisofcarbondepositonpistonafterbenchtestondieseloilwithsulfurcontentabout011%?6S?;?018%?O?Q?XPS?L?F6S?XSyfff18%9112008?H1?u?X:?;?.?)?8227igPanalsisocarbondepositonpistonaterbenchtestondieseloilwithsulurcontentabout07S?2?;?u?E?5?o?2?L?8Fig7S?Sulfidefor
12、mdistributionincarbondepositproducedbytwodieseloilswithdifferentsulfurcontentS?5S2?6?2?,?;?u?E?5,?Q?/?z?cCS2OS2PS2S,?n?;?T?)S0?7?5?,?(018%)?-?(?;?011%)?u?E?5,?o?2?;?)?N?0?)S0?(018%)?u?E?5SO2?2?7718%,?A?2?o?5?2112%,?)?c?-?(011%)?u?E?5?j?L?3?TS0?o,?Q?I?C?,?O?v?u?S?,?T?a?S0?,?B?L?K,?O?a?u?E?K?)?.,?)?.?
13、R?)?0S021213S?K?.?;?K011%?018%?YS1135?W?K?A?,?8?.?T?A?;?,?3S0?3S?K?5?)?Table3S?Thecomparisionoflubricantperformanceinenginebenchtest?/h?100e8/(mm2?s-1)011%S018%S?;?/%011%S018%S?q/(mgKOH?g-1)011%S018%S?Q?q/(mgKOH?g-1)011%S018%S011188811188801310013100131013151635163CC305011153411151801311013120132012
14、2znzn10011155911152701313013110134013051695172014160914160901409014090152015210151015CC4050141460141450013940143001590146znzn10014146314149101394014030164014910161016014129314129301329013290120012081218121CD4050141203141158zn0132601230130znzn10014117514118901319013260133013781309136?-?.0131037131037
15、01522015220127012710151015?50121888121943015330152801280140znzn?K?10012186512194801525015230136014410181018?:?RGB/T265?;?;?RGB/T387?;?q?RGB/T264?;?Q?q?RSH/T0251?S0S?3?C?,2?4?F?O?K?S2?;?S2?q?Q?q?M?R?o,?Q?T?O?vS0?c?K?(?100h),?K?.?T?-?u?)?o,?o?R?S0?3?C?,?n?l?CD40?-?.?K?q?c?v?(012e?013e?0137mgKOH/g;0127
16、e?11KO),?O?5?)?L?-,?,?.?;?,?.?q?3?L?)?,?5?l?K?q?S03S?I?L?,?L?5?o?,?.?;?C,?K?)?S0?;?,?-?;?A?,?u?E?/?z?E?/?z?L?;?o?T?),?Q?K?;?.?)?.,?d?c?5?o?2?T?FS0?O?a?u?E?K?)?.,?A?K?)?.?K?O?,?n?z021?O?2?H33?8040044mgH/g;?u?EH2SO4,?%?j?.?W?n?1?4?I,?u?K?;?E,?,?%?.?I,?K?;?R?)?o?.?n?b?5,?X?W?,?M?S?9?K?,?K?(?X?,?A?%?.?,
17、?W?j?,?E?w,?w?E,?7?1?Y?u?,?9?u?,?9?S0?,?5?o?;?T?S04S?(1)?L?5?o?,?;?T?-?)S0(2)?;?,?5?K?)?.?;?),?K?O?,?,?K?T?0?.?;?S0(3)?K?.?,?R?.?qS2?3?L?)?K?S0?8?fSE1SGGB25222000?S.SE2SGMIL2F216884?L?S.SE3SG?:?.?5?o?B?M.?l?:?5?o?Y?v,1991:44-57.SE4SGGB/T509621991?M?S.SE5SGSH/T0261294CD?K?9?3?)?(1135D2?)S.SE6SGSH/T00
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