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1、 ，如果你需要更多标准可以到 如果你购买的文档存在缺页、字迹模糊、乱码等情况，请大家通过论坛消息与我联系。BRITISH STANDARDBS EN 12672:2008Licensed Copy: x x, The University of Sheffield, 01/07/2009 16:12, Uncontrolled Copy, (c) BSIChemicals usedfor treatment of water intended for human consumption PotassiumpermanganateICS 13.060.20; 71.100.80NO COPYIN
2、G WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBS EN 12672:2008National forewordThis British Standard is the UK implementation of EN 12672:2008. It supersedes BS EN 12672:2000 which is withdrawn.The UK participation in its preparation was entrusted to TechnicalCommittee CII/59, Chemica
3、ls for drinking water treatment.A list of organizations represented on this committee can be obtained on request to its secretary.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application.Compliance with a British Stand
4、ard cannot confer immunity from legal obligations.Licensed Copy: x x, The University of Sheffield, 01/07/2009 16:12, Uncontrolled Copy, (c) BSIThis British Standard was published under the authority of the Standards Policy and Strategy Committee on 31 May 2009 BSI 2009ISBN 978 0 580 58049 9Amendment
5、s/corrigenda issued since publicationDate CommentsBS EN 12672:2008EUROPEAN STANDARD NORME EUROPENNEEUROPISCHE NORMEN 12672July 2008ICS 71.100.80Supersedes EN 12672:2000English VersionChemicals used for treatment of water intended for human consumption - Potassium permanganateProduits chimiques utili
6、ss pour le traitement de leau destine la consommation humaine - Parmanganate de potassiumProdukte zur Aufbereitung von Wasser fr den menschlichen Gebrauch - KaliumpermanganatThis European Standard was approved by CEN on 28 June 2008.CEN members are bound to comply with the CEN/CENELEC Internal Regul
7、ations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN Management Centre or to any CEN member.This E
8、uropean Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as the official versions.CEN members are the
9、national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland
10、and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATION C OM I T EUR OP EN DE NOR M AL I S ATI ON EUR OP I S C HES KOM I TEE F R NOR M UNG Management Centre: rue de Stassart, 36 B-1050 BrusselsLicensed Copy: x x, The University of Sheffield, 01/07/2009 16:12, Uncontrolled Copy, (c) BSI 2008 CENAll
11、 rights of exploitation in any form and by any means reserved worldwide for CEN national Members.Ref. No. EN 12672:2008: ELicensed Copy: x x, The University of Sheffield, 01/07/2009 16:12, Uncontrolled Copy, (c) BSIContentsPageForeword3Introduction41 Scope52 Normative references53 Description54 Puri
12、ty criteria85 Test methods96 Labelling - Transportation - Storage14Annex A (informative) General information on potassium permanganate16Annex B (normative) General rules relating to safety18Bibliography2013BS EN 12672:2008EN 12672:2008 (E)Licensed Copy: x x, The University of Sheffield, 01/07/2009 1
13、6:12, Uncontrolled Copy, (c) BSIForewordThis document (EN 12672:2008) has been prepared by Technical Committee CEN/TC 164 “Water supply”, the secretariat of which is held by AFNOR.This European Standard shall be given the status of a national standard, either by publication of an identical text or b
14、y endorsement, at the latest by January 2009, and conflicting national standards shall be withdrawn at the latest by January 2009.Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for
15、 identifying any or all such patent rights.This document supersedes EN 12672:2000.Significant technical difference between this edition and EN 12672:2000 is as follows: Deletion of reference to EU Directive 80/778/EEC of July 15, 1980 in order to take into account the latestDirective in force (see 1
16、).According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy
17、, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom.Licensed Copy: x x, The University of Sheffield, 01/07/2009 16:12, Uncontrolled Copy, (c) BSIIntroductionIn respect of potential adverse effec
18、ts on the quality of water intended for human consumption, caused by the product covered by this European Standard:a)this European Standard provides no information as to whether the product may be used without restriction in any of the Member States of the EU or EFTA;b)it should be noted that, while
19、 awaiting the adoption of verifiable European criteria, existing national regulations concerning the use and/or the characteristics of this product remain in force.NOTEConformity with this European Standard does not confer or imply acceptance or approval of the product in any of the Member States of
20、 the EU or EFTA. The use of the product covered by this European Standard is subject to regulation or control by National Authorities.Licensed Copy: x x, The University of Sheffield, 01/07/2009 16:12, Uncontrolled Copy, (c) BSI1ScopeThis European Standard is applicable to potassium permanganate used
21、 for treatment of water intended for human consumption. It describes the characteristics of potassium permanganate and specifies the requirements and the corresponding test methods for potassium permanganate. It gives information on its use in water treatment.2Normative referencesThe following refer
22、enced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies.EN 1233, Water quality - Determination of chromium - Atomic absorptio
23、n spectrometric methodsEN 1483, Water quality - Determination of mercury Method using atomic absorption spectrometryEN ISO 3696, Water for analytical laboratory use - Specification and test methods (ISO 3696:1987)EN ISO 11885, Water quality - Determination of 33 elements by inductively coupled plasm
24、a atomic emission spectroscopy (ISO 11885:1996)EN ISO 11969, Water quality - Determination of arsenic Atomic absorption spectrometric method (hydride technique) (ISO 11969:1996)ISO 3165, Sampling of chemical products for industrial use - Safety in samplingISO 3856-2, Paints and varnishes - Determina
25、tion of soluble metal content - Part 2: Determination of antimony content - Flame atomic absorption spectrometric method and Rhodamine B spectrophotometric methodISO 6206, Chemical products for industrial use - Sampling VocabularyISO 8213, Chemical products for industrial use - Sampling techniques -
26、 Solid chemical products in the form of particles varying from powders to coarse lumpsISO 8288:1986, Water quality - Determination of cobalt, nickel, copper, zinc, cadmium and lead - Flame atomic absorption spectrometric methodsISO 9965, Water quality - Determination of selenium - Atomic absorption
27、spectrometric method (hydride technique)3Description3.1 Identification3.1.1Chemical namePotassium permanganate.3.1.2Synonym or common namePermanganate of potash.3.1.3Relative molecular mass158,04Licensed Copy: x x, The University of Sheffield, 01/07/2009 16:12, Uncontrolled Copy, (c) BSI3.1.4Empiric
28、al formulaKMnO43.1.5Chemical formulaKMnO43.1.6CAS Registry Number 1)7722-64-73.1.7EINECS reference 2)231-760-33.2 Commercial formsSolid product, consisting of rhombic crystals. For water treatment the commercial forms normally used are: technical grade to be dosed in liquid form, dissolved in water;
29、 free-flowing grade to be dosed either in solid form or dissolved in water.3.3 Physical properties3.3.1AppearanceCrystals of a dark purple or bronze-like colour; almost opaque by transmitted light and of a blue metallic lustre by reflected light.The free-flowing grade can present a different colour,
30、 usually greyish.3.3.2DensityThe density of the product is 2,70 g/cm3 at 20 C.The bulk density is between 1,45 g/cm3 and 1,60 g/cm3.1) Chemicals Abstracts Service Registry Number.2) European Inventory of Existing Commercial Chemical Substances.Licensed Copy: x x, The University of Sheffield, 01/07/2
31、009 16:12, Uncontrolled Copy, (c) BSI3.3.3Solubility (in water)The product is soluble in water.The solubility in water is given in Table 1. Aqueous solubility:KMnO4 (g/l )= 30.55 + 0.796 (T, C) + 0.0392 (T, C)2 whereTis the Solution Temperature (C).Table 1 Solubility in waterTemperatureCKMnO4g/l535,
32、511042,431551,312062,152574,953089,713.3.4Vapour pressureNot applicable.3.3.5Boiling point at 100 kPa3)Not applicable.3.3.6Melting pointProduct decomposes at 240 C with emission of oxygen.3.3.7Specific heat744,2 kJ/kg.K at 20 C.3.3.8Viscosity (dynamic)Not applicable.3.3.9Critical temperatureNot appl
33、icable.3) 100 kPa = 1 barLicensed Copy: x x, The University of Sheffield, 01/07/2009 16:12, Uncontrolled Copy, (c) BSI3.3.10 Critical pressureNot applicable.3.3.11 Physical hardnessNot applicable.3.4 Chemical propertiesPotassium permanganate is a very strong oxidizing agent.It is soluble in water an
34、d dissolves also in various organic solvents (e.g. methanol, ethanol).It decomposes at high temperature and also in the presence of concentrated acids, hydrogen peroxide and organic compounds in general.It hydrolyzes in contact with air, reducing to manganese dioxide (MnO2), a solid, brown to black
35、colour product.4Purity criteria4.1 GeneralThis European Standard specifies the minimum purity requirements for Potassium permanganate used for the treatment of water intended for human consumption. Limits are given for impurities commonly present in the product. Depending on the raw material and the
36、 manufacturing process other impurities may be present and, if so, this shall be notified to the user and when necessary to relevant authorities.NOTEUsers of this product should check the national regulations in order to clarify whether it is of appropriate purity for treatment of water intended for
37、 human consumption, taking into account raw water quality, required dosage, contents of other impurities and additives used in the product not stated in the product standard.Limits have been given for impurities and chemicals parameters where these are likely to be present in significant quantities
38、from the current production process and raw materials. If the production process or raw materials leads to significant quantities of impurities, by-products or additives being present, this shall be notified to the user.4.2 Composition of commercial productThe potassium permanganate content shall no
39、t be less than a mass fraction of 98,5 % in the technical grade, and a mass fraction of 97,5 % in the free-flowing grade.4.3 Impurities and main by-productsMnO2 (water insolubles): less than a mass fraction of 1,00 %. Moisture (H2O): less than a mass fraction of 0,50 %.4.4 Chemical parametersNOTEFor
40、 the purpose of this standard, chemical parameters are those defined in the EU Directive 98/83/EC of 3November 1998 (see 1).The content of chemical parameters shall conform to the requirements specified in Table 2.Licensed Copy: x x, The University of Sheffield, 01/07/2009 16:12, Uncontrolled Copy,
41、(c) BSITable 2 Chemical parametersParameterLimit mg/kgof productArsenic (As)max. Cadmium (Cd)max. Chromium (Cr)max. Mercury (Hg)max. Nickel (Ni)max. Lead (Pb)max. Antimony (Sb)max.Selenium (Se)max.2050501050505050NOTECyanide, which does not exist in a strong oxidizing medium such as potassium perman
42、ganate, is not a relevant chemical parameter. Pesticides and polycyclic aromatic hydrocarbons are not by-products of the manufacturing process.4.5 Flowability of freeflowing gradeThe free-flowing grade shall pass the flowability test.5Test methods5.1 SamplingObserve the general recommendations of IS
43、O 3165 and take account of ISO 6206. Prepare the laboratory sample(s) required by the relevant procedure described in ISO 8213.5.2 Analysis5.2.1Determination of potassium permanganate (main product)5.2.1.1PrincipleReduction of potassium permanganate Mn(VII) to Mn(II) with sodium oxalate under acidic
44、 conditions. The excess of sodium oxalate is titrated with a standard volumetric solution of potassium permanganate.5.2.1.2ReagentsAll reagents shall be of a recognized analytical grade and the water used shall conform to grade 3 in accordance with EN ISO 3696.5.2.1.2.1Potassium permanganate.5.2.1.2
45、.2Sodium oxalate.5.2.1.2.3Sulfuric acid solution, 20 % (m/m).5.2.1.2.4Potassium permanganate standard volumetric solution c(KMnO4) = 1,000 g/l. Weigh 1,000 g of the potassium permanganate (5.2.1.2.1), transfer to a 1 l volumetric flask and dilute to volume with water. Allow to stand with occasional mixing for 15 min.Standardize the solution as follows: Weigh 2,120 g of the sodium oxalate (5.2.1.2.2) and transfer to a 1 l