BS-EN-ISO-4526-2004.pdf

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1、BRITISH STANDARD BS EN ISO 4526:2004 Incorporating Amendment No. 1 to BS ISO 4526:2004 (renumbers BS ISO as BS EN ISO 4526:2004) Metallic coatings Electroplated coatings of nickel for engineering purposes The European Standard EN ISO 4526:2004 has the status of a British Standard ICS 25.220.40 ? Lic

2、ensed Copy: sheffieldun sheffieldun, na, Sun Nov 19 12:44:45 GMT+00:00 2006, Uncontrolled Copy, (c) BSI BS EN ISO 4526:2004 This British Standard was published under the authority of the Standards Policy and Strategy Committee on 5 January 2005 BSI 2006 ISBN 0 580 45168 2 National foreword This Brit

3、ish Standard is the English language version of EN ISO 4526:2004. It is identical with ISO 4526:2004. The UK participation in its preparation was entrusted to Technical Committee STI/33, Electrodeposited and related coatings, which has the responsibility to: A list of organizations represented on th

4、is committee can be obtained on request to its secretary. Cross-references The British Standards which implement international publications referred to in this document may be found in the BSI Catalogue under the section entitled “International Standards Correspondence Index”, or by using the “Searc

5、h” facility of the BSI Electronic Catalogue or of British Standards Online. This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. Compliance with a British Standard does not of itself confer immunity from legal obl

6、igations. aid enquirers to understand the text; present to the responsible international/European committee any enquiries on the interpretation, or proposals for change, and keep UK interests informed; monitor related international and European developments and promulgate them in the UK. Summary of

7、pages This document comprises a front cover, an inside front cover, the EN ISO title page, the EN ISO foreword page, the ISO title page, pages ii to v, a blank page, pages 1 to 14, an inside back cover and a back cover. The BSI copyright notice displayed in this document indicates when the document

8、was last issued. Amendments issued since publication Amd. No. DateComments 1579828 April 2006Renumbers BS ISO 4526:2004 as BS EN ISO 4526:2004 Licensed Copy: sheffieldun sheffieldun, na, Sun Nov 19 12:44:45 GMT+00:00 2006, Uncontrolled Copy, (c) BSI EUROPEANSTAND ARD NORMEEUROPENNE EUROPI SCHENORM E

9、 NI SO4526 J une 2 004 I CS 2 5. 2 2 0. 40 Eng l ish version Metal l ic coating s El ectropl ated coating s of nickelf or eng ineeringpurposes ( I SO 452 6:2 004) Revtements mtal l iq ues D epts l ectrol ytiq ues de nickel pour usag es industriel s ( I SO 452 6:2 004) This European Standard was appr

10、oved by CEN on 1 3 May 2 004. CEN members are bound to compl y with the CEN/CENEL EC I nternalReg ul ations which stipul ate the conditions f or g iving this European Standard the status of a national standard without any al teration.Up-to-date l ists and bibl iog raphical ref erences concerning suc

11、h national standards may be obtained on appl ication to the CentralSecretariat or to any CEN member. This European Standard exists in three of f icial versions ( Eng l ish,French,German).A version in any other l ang uag e made by transl ation under the responsibil ity of a CEN member into its own l

12、ang uag e and notif ied to the CentralSecretariat has the same status as the of f icial versions. CEN members are the national standards bodies of Austria,Bel g ium,Cyprus,Czech Republ ic,D enmark,Estonia,Finl and,France, Germany,Greece,Hung ary,I cel and,I rel and,I tal y,L atvia,L ithuania,L uxemb

13、ourg ,Mal ta,Netherl ands,Norway,Pol and,Portug al ,Sl ovakia, Sl ovenia,Spain,Sweden,Switzerl and and United King dom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Manage me nt Ce ntre : rued eStas s art, 36 B-1050 Brus s e l s 2 004 CENAl l r

14、ig hts of expl oitation in any f orm and by any means reserved worl dwide f or CEN nationalMembers. Ref .No.EN I SO 452 6:2 004: E Licensed Copy: sheffieldun sheffieldun, na, Sun Nov 19 12:44:45 GMT+00:00 2006, Uncontrolled Copy, (c) BSI Foreword This document (EN ISO 4526:2004) has been prepared by

15、 Technical Committee ISO/TC 107, Metallic and other inorganic coatings, in collaboration with Technical Committee CEN/TC 262, Metallic and other inorganic coatings, the secretariat of which is held by BSI. This European Standard shall be given the status of a national standard, either by publication

16、 of an identical text or by endorsement, at the latest by December 2004, and conflicting national standards shall be withdrawn at the latest by December 2004. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement thi

17、s European Standard: Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. Endorse

18、ment notice The text of ISO 4526:2004 has been approved by CEN as EN ISO 4526:2004 without any modifications. EN ISO 4526:2004 Licensed Copy: sheffieldun sheffieldun, na, Sun Nov 19 12:44:45 GMT+00:00 2006, Uncontrolled Copy, (c) BSI Reference number ISO 4526:2004(E) OSI 4002 INTERNATIONAL STANDARD

19、ISO 4526 Second edition 2004-05-15 Metallic coatings Electroplated coatings of nickel for engineering purposes Revtements mtalliques Dpts lectrolytiques de nickel pour usages industriels EN ISO 4526:2004 Licensed Copy: sheffieldun sheffieldun, na, Sun Nov 19 12:44:45 GMT+00:00 2006, Uncontrolled Cop

20、y, (c) BSI ii EN ISO 4526:2004 Licensed Copy: sheffieldun sheffieldun, na, Sun Nov 19 12:44:45 GMT+00:00 2006, Uncontrolled Copy, (c) BSI I SO 4002 All irthgs ersedevr iii Contents Page Forewordiv Introduction v 1 Scope 1 2 Normative references . 1 3 Terms and definitions. 2 4 Information to be supp

21、lied to the electroplater . 2 5 Designation 3 6 Requirements 6 7 Sampling 8 Annex A (informative) Typical composition and operating conditions of Watts and nickel sulfamate solutions, and mechanical properties of nickel electrodeposited from those solutions 9 Annex B (informative) Test methods for d

22、etermining thickness. 10 Annex C (normative) Hot water porosity test 11 Annex D (normative) Modified ferroxyl test. 12 Annex E (informative) Additional information for different applications 13 Bibliography . 14 EN ISO 4526:2004 Licensed Copy: sheffieldun sheffieldun, na, Sun Nov 19 12:44:45 GMT+00:

23、00 2006, Uncontrolled Copy, (c) BSI IS:6254 O4002(E) iv I SO 4002 All irthgs ersedevr Foreword ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out th

24、rough ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collab

25、orates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2. The main task of technical committees is to prepare International Stan

26、dards. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by at least 75 % of the member bodies casting a vote. Attention is drawn to the possibility that some of the elements of

27、 this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. ISO 4526 was prepared by Technical Committee ISO/TC 107, Metallic and other inorganic coatings, Subcommittee SC 3, Electrodeposited coatings and related finishes. This

28、 second edition cancels and replaces the first edition (ISO 4526:1984), which has been technically revised. EN ISO 4526:2004 Licensed Copy: sheffieldun sheffieldun, na, Sun Nov 19 12:44:45 GMT+00:00 2006, Uncontrolled Copy, (c) BSI I SO 4002 All irthgs ersedevr v Introduction Engineering nickel coat

29、ings are specified for various applications such as improved hardness, wear and corrosion resistance, load-bearing characteristics, heat-scaling resistance, corrosion fatigue resistance and other improvements in surface properties. Electrodeposited nickel is also, used in engineering applications to

30、 salvage worn or incorrectly machined manufactured articles, and function as diffusion barriers in combination with other metallic coatings. Engineering nickel coatings usually contain greater than 99 % nickel and are most frequently electrodeposited from additive-free Watts or nickel sulfamate solu

31、tions. Typical solution compositions, operating conditions and mechanical properties of electrodeposits from these solutions are given in Annex A. When increased hardness, greater wear resistance, modified deposit internal stress values and enhanced levelling characteristics are required, particles

32、of organic additives such as silicon carbide, tungsten carbide, aluminium oxide, chromium carbide and other substances may be introduced into these solutions. The use of sulfur-containing organic additives to increase hardness and to lower residual internal stress is feasible only when the end-use i

33、nvolves exposure to low or moderate temperatures. High temperature exposure of nickel coatings that contain sulfur may result in embrittlement and cracking of the coating. The effect is time- dependent and may become evident at 150 C if the time of heating is sufficiently long. A notable trend is th

34、e growing utilisation of nickel alloy electroplating processes for engineering applications. These include binary alloys of nickel with cobalt, iron, manganese, molybdenum, phosphorus and tungsten. EN ISO 4526:2004 Licensed Copy: sheffieldun sheffieldun, na, Sun Nov 19 12:44:45 GMT+00:00 2006, Uncon

35、trolled Copy, (c) BSI blank Licensed Copy: sheffieldun sheffieldun, na, Sun Nov 19 12:44:45 GMT+00:00 2006, Uncontrolled Copy, (c) BSI INTENRATIONAL TSANDADR IS:6254 O4002(E) I SO 4002 All irthgs ersedevr 1 Metallic coatings Electroplated coatings of nickel for engineering purposes 1 Scope This Inte

36、rnational Standard specifies requirements for electroplated nickel and nickel alloy coatings applied to ferrous and non-ferrous basis metals for engineering purposes. Binary nickel alloys in which nickel is a minor constituent are outside the scope of this International Standard. The designation pro

37、vides a means of specifying the type and thickness of nickel and nickel alloy coatings appropriate for engineering applications. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For

38、 undated references, the latest edition of the referenced document (including any amendments) applies. ISO 1463, Metallic and oxide coatings Measurement of coating thickness Microscopical method ISO 2064, Metallic and other inorganic coatings Definitions and conventions concerning the measurement of

39、 thickness ISO 2079, Surface treatment and metallic coatings General classification of terms ISO 2080, Electroplating and related processes Vocabulary ISO 2177, Metallic coatings Measurement of coating thickness Coulometric method by anodic dissolution ISO 2361, Electrodeposited nickel coatings on m

40、agnetic and non-magnetic substrates Measurement of coating thickness Magnetic method ISO 2819, Metallic coatings on metallic substrates Electrodeposited and chemically deposited coatings Review of methods available for testing adhesion ISO 3497, Metallic coatings Measurement of coating thickness X-r

41、ay spectrometric methods ISO 3543, Metallic and non-metallic coatings Measurement of thickness Beta backscatter method ISO 3882, Metallic and other inorganic coatings Review of methods of measurement of thickness ISO 4516, Metallic and other inorganic coatings Vickers and Knoop microhardness tests I

42、SO 4519, Electrodeposited metallic coatings and related finishes Sampling procedures for inspection by attributes ISO 8401, Metallic coatings Review of methods of measurement of ductility ISO 9220, Metallic coatings Measurement of coating thickness Scanning electron microscope method EN ISO 4526:200

43、4 Licensed Copy: sheffieldun sheffieldun, na, Sun Nov 19 12:44:45 GMT+00:00 2006, Uncontrolled Copy, (c) BSI IS:6254 O4002(E) 2 I SO 4002 All irthgs ersedevr ISO 9587, Metallic and other inorganic coatings Pretreatments of iron or steel to reduce the risk of hydrogen embrittlement ISO 9588, Metallic

44、 and other inorganic coatings Post-coating treatments of iron or steel to reduce the risk of hydrogen embrittlement ISO 10289, Methods for corrosion testing of metallic and other inorganic coatings on metallic substrates Rating of test specimens and manufactured articles subjected to corrosion tests

45、 ISO 10587, Metallic and other inorganic coatings Test for residual embrittlement in both metallic-coated and uncoated externally-threaded articles and rods Inclined wedge method ISO 12686, Metallic and other inorganic coatings Automated controlled shot-peening of metallic articles prior to nickel,

46、autocatalytic nickel or chromium plating, or as a final finish ISO 15724, Metallic and other inorganic coatings Electrochemical measurement of diffusible hydrogen in steels Barnacle electrode method EN 12508, Corrosion protection of metals and alloys Surface treatment, metallic and other inorganic c

47、oatings Vocabulary 3 Terms and definitions For the purposes of this document, the terms and definitions given in ISO 2064, ISO 2079, ISO 2080 and EN 12508 apply. 4 Information to be supplied to the electroplater 4.1 Essential information When ordering articles to be electroplated, in accordance with

48、 this International Standard, the purchaser shall provide the following information in writing, e.g. in the contract or purchase order, or on engineering drawings. a) The designation (see Clause 5). b) The requirements for special test specimens (see 6.1). c) The significant surface, indicated by dr

49、awings of the articles or by suitably marked samples (see 6.2). d) The final surface finish, e.g. as-plated, ground, machined or polished. Alternatively, samples showing the required finish shall be supplied or approved by the purchaser, and used for comparison purposes (see 6.2 and 6.3). e) The type and size of defects with the number of defects that can be tolerated per item, for the surface or per square dec

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