《BS-EN-71-5-1993 BS-5665-5-1993.pdf》由会员分享，可在线阅读，更多相关《BS-EN-71-5-1993 BS-5665-5-1993.pdf（74页珍藏版）》请在三一文库上搜索。
1、? BRITISH STANDARD BS EN 71-5:1993 BS 5665-5: 1993 Incorporating Amendment No. 1 Safety of toys Part 5: Chemical toys (sets) other than experimental sets The European Standard EN 71-5:1993, with the incorporation of amendment A1:2006, has the status of a British Standard UDC 688.72:54:614.8:620.1 BS
2、 EN 71-5:1993 This British Standard, having been prepared under the direction of the Textiles and Clothing Standards Policy Committee, was published under the authority of the Standards Board and comes into effect on 15 August 1993 BSI 2006 The following BSI references relate to the work on this sta
3、ndard: Committee reference TCM/15 Draft for comment 90/43128 DC ISBN 0 580 20239 9 Cooperating organizations The European Committee for Standardization, under whose supervision this European Standard was prepared, comprises the national standards organizations of the following Western European count
4、ries: AustriaOesterreichisches Normungsinstitut BelgiumInstitut belge de normalisation DenmarkDansk Standardiseringsraad FinlandSuomen Standardisoimisliito, r.y. FranceAssociation franaise de normalisation GermanyDeutsches Institut fr Normung e.V. GreeceHellenic Organization for Standardization Icel
5、and Technological Institute of Iceland IrelandNational Standards Authority of Ireland ItalyEnte Nazionale Italiano di Unificazione LuxembourgInspection du Travail et des Mines NetherlandsNederlands Normalisatie-instituut NorwayNorges Standardisringsforbund PortugalInstituto Portugus da Qualidade Spa
6、inAsociacin Espaola de Normalizacin y Certificacin SwedenStandardiseringskommissionen i Sverige SwitzerlandAssociation suisse de normalisation United KingdomBritish Standards Institution Amendments issued since publication Amd. No.DateComments 1624031 May 2006See national foreword BS EN 71-5:1993 BS
7、I 2006i Contents Page Cooperating organizationsInside front cover National forewordii EN foreword2 Text of EN 71-55 National appendix NA68 National appendix NBInside back cover BS EN 71-5:1993 ii BSI 2006 National foreword This British Standard has been prepared under the direction of the Textiles a
8、nd Clothing Standards Policy Committee. It is the English language version of EN 71-5 Safety of toys: Part 5:1993 Chemical toys (sets) other than experimental sets, published by the European Committee for Standardization (CEN). This standard forms Part 5 of EN 71, including amendment A1:2006. The re
9、maining Parts of EN 71 are presently published as Parts of BS 5665 Safety of toys but on revision will be published under the designation BS EN 71. The start and finish of text introduced or altered by CEN amendment is indicated in the text by tags !“. Tags indicating changes to CEN text carry the n
10、umber of the CEN amendment. For example, text altered by CEN amendment A1 is indicated in the text by !“. A British Standard does not purport to include all the necessary provisions of a contract. Users of British Standards are responsible for their correct application. Compliance with a British Sta
11、ndard does not of itself confer immunity from legal obligations. In particular the attention of users is drawn to the Toys (Safety) Regulations 1989 (SI 1275). Summary of pages This document comprises a front cover, an inside front cover, pages i and ii, the EN title page, pages 2 to 76, an inside b
12、ack cover and a back cover. This standard has been updated (see copyright date) and may have had amendments incorporated. This will be indicated in the amendment table on the inside front cover. EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 71-5 May 1993 +A1 January 2006 UDC 688.72:54:614.8:6
13、20.1 Descriptors: Toys, games, chemical compounds, safety requirements, accident prevention, dangerous material, approved doses, specifications, packing, marking English version Safety of toys Part 5: Chemical toys (sets) other than experimental sets (includes amendment A1:2006) Scurit des jouets Pa
14、rtie 5: Jeux chimiques (coffrets) autres que les coffrets dexpriences chimiques (inclut lamendement A1:2006) Sicherheit von Spielzeug Teil 5: Chemisches Spielzeug (Sets) ausgenommen Experimentierksten (enthlt nderung A1:2006) This European Standard was approved by CEN on 1993-05-14. Amendment A1 was
15、 approved by CEN on 2005-12-07. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationa
16、l standards may be obtained on application to the Central Secretariat or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notif
17、ied to the Central Secretariat has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Denmark, Finland, France, Germany, Greece, Iceland, Ireland, Italy, Luxembourg, Netherlands, Norway, Portugal, Spain, Sweden, Switzerland and United Kingdom
18、. CEN European Committee for Standardization Comit Europen de Normalisation Europisches Komitee fr Normung Central Secretariat: rue de Stassart 36, B-1050 Brussels 1993 Copyright reserved to CEN members Ref. No. EN 71-5:1993 + A1:2006 E EN 71-5-1993 BSI 2006 2 Foreword This European Standard was dra
19、wn up by the Technical Committee CEN/TC 52/WG 5 “Safety of toys Chemical toys”, the secretariat of which is held by DS. This standard was submitted for the second Formal Vote, and the result was positive. This European Standard has been prepared under a mandate given to CEN by the Commission of the
20、European Communities and the European Free Trade Association, and supports essential requirements of EC Directive(s). This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by November 1993, and conflicting
21、 national standards shall be withdrawn at the latest by November 1993. According to the CEN/CENELEC Internal Regulations, the following countries are bound to implement this European Standard: Austria, Belgium, Denmark, Finland, France, Germany, Greece, Iceland, Ireland, Italy, Luxembourg, Netherlan
22、ds, Norway, Portugal, Spain, Sweden, Switzerland, United Kingdom. Foreword to amendment A1 This European Standard (EN 71-5:1993/A1:2006) has been prepared by Technical Committee CEN/TC 52 “Safety of toys”, the secretariat of which is held by DS. This Amendment to the European Standard EN 71-5:1993 s
23、hall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by July 2006, and conflicting national standards shall be withdrawn at the latest by July 2006. This European Standard has been prepared under a mandate given to CEN by the Eu
24、ropean Commission and the European Free Trade Association, and supports essential requirements of EU Directive(s). For relationship with EU Directive(s), see informative Annex ZA, which is an integral part of this European Standard. According to the CEN/CENELEC Internal Regulations, the national sta
25、ndards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,
26、Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. Contents Page Introduction5 1Scope5 2Normative references6 3Definitions6 4Plaster of Paris (gypsum) moulding sets7 5Ceramic and vitreous enamelling materials supplied in miniature workshop sets7 6Oven hardening plasticized P
27、VC-modelling clay sets8 7Plastic moulding sets9 8Photographic processing sets9 9Adhesives, paints, lacquers, varnishes, thinners and cleaning agents (solvents) supplied or recommended in model sets10 10Marking15 11Instructions for use15 12Test methods16 Annex A (normative) Environmental, health and
28、safety precautions61 Annex B (informative) Solvent content in different matrices and permitted maximum concentration62 Annex C (informative) Preliminary test method for the determination of elements in ceramic and vitreous enamelling materials63 Annex D (informative) Validation of test methods64 Ann
29、ex ZA (informative) Clauses of this European Standard addressing essential requirements or other provisions of EU Directives.65 Bibliography66 Figure 1 Total ion chromatogram of a mixture of phthalates21 Figure 2 Total ion chromatogram of a mixture of phthalates22 Figure 3 IR-spectrum of sodium disu
30、lfite Na2SO532 Figure 4 IR-spectrum of sodium sulfite Na2SO333 Figure 5 Chromatogram of organic acids36 Figure 6 Chromatogram of N-(4-hydroxyphenyl)glycine, N-methyl-p-amino- phenol and 1-phenyl-pyrazolidin-3-one38 BS EN 71-5:1993 BSI 20063 Page Figure 7 Chromatogram of a mixture of organic solvents
31、 by HS-GC-FID using a 60 m 0,32 mm 0,50 m polar column (ZB-WAX)50 Figure 8 Chromatogram of a mixture of organic solvents by HS-GC-FID using a 60 m 0,32 mm 1,00 m non-polar column ZB-151 Figure 9 Chromatogram: Total ion chromatogram of a mixture of organic solvents by GC-MSD52 Figure 10 FTIR-spectrum
32、 of nitrocellulose in reflection mode55 Figure 11 Chromatogram of film-forming agent substances 1 to 957 Figure 12 Chromatogram of film-forming agent Luwax E58 Table 1 Chemical preparations8 Table 2 Plasticizers8 Table 3 Polystyrene9 Table 4 Maximum amounts of chemical substances10 Table 5 Basic mat
33、erials for water-based adhesives and water-based paints and lacquers11 Table 6 Special materials for adhesives for paper and wood and water-based paints and lacquers11 Table 7 Special additives for liquid adhesives for paper and wood11 Table 8 Special material for adhesive sticks for paper12 Table 9
34、 Basic materials for multi-purpose adhesives12 Table 10 Basic materials for contact adhesives12 Table 11 Basic materials for special adhesives12 Table 12 Solvents13 Table 13 Organic solvents and film forming agents13 Table 14 Basic materials14 Table 15 Solvents14 Table 16 Standards17 Table 17 Reagen
35、ts17 Table 18 Wavelengths17 Table 19 Conversion factors18 Table 20 Phthalic acid esters20 Table 21 Adipic acid polyesters20 Page Table 22 Citric acid esters20 Table 23 Alkylsulfonic acid esters20 Table 24 Solvents20 Table 25 Stock solutions I22 Table 26 Stock solutions II23 Table 27 Calibration solu
36、tions23 Table 28 Standards26 Table 29 Solvents26 Table 30 Standard28 Table 31 Reagents28 Table 32 Inorganic substances in photographic sets29 Table 33 Standard30 Table 34 Reagents30 Table 35 Standards30 Table 36 Reagent30 Table 37 Standards30 Table 38 Reagents30 Table 39 Standards31 Table 40 Standar
37、ds31 Table 41 Standards31 Table 42 Reagents31 Table 43 Standard31 Table 44 Reagent31 Table 45 Standards33 Table 46 Reagents33 Table 47 Standards34 Table 48 Reagents34 Table 49 Organic substances in photographic sets35 Table 50 Standards35 Table 51 Reagents35 Table 52 Sequence of elution36 Table 53 S
38、tandards37 Table 54 Reagents37 Table 55 Sequence of elution37 Table 56 Standards38 Table 57 Reagents38 Table 58 Solvents / identification40 Table 59 Solvents / determination41 Table 60 Solvents42 Table 61 Reagents42 Table 62 Organic solvents for analysis by HS-GC-FID44 Table 63 Organic solvents for
39、analysis by GC-MS44 BS EN 71-5:1993 4 BSI 2006 Page Table 64 Working solution 144 Table 65 Working solution 244 Table 66 Working solution 344 Table 67 Working solution 444 Table 68 Working solution 545 Table 69 Calibration solutions in saline for aqueous-based materials45 Table 70 Calibration soluti
40、ons in DMF for solvent-based materials45 Table 71 Calibration solutions for the determination of solvents using HS-GC-FID45 Table 72 Calibration solutions in DMF or saline for hexane46 Table 73 Calibration solutions in DMF for 1-methoxypropan-2-ol46 Table 74 Calibration solutions in saline for 1-met
41、hoxypropan-2-ol, ethanol and propan-2-ol46 Table 75 Calibration solutions for identification of solvents by GC-MS47 Table 76 Calibration solutions for 2-(2-butoxyethoxy)ethyl acetate47 Table 77 Calibration solutions for butyl glycolate47 Table 78 Calibration solutions for (-caprolactam47 Table 79 Ca
42、libration solutions for 2-methylpentane-2,4-diol47 Page Table 80 Calibration solutions for the determination of propane-1,2-diol by GC-FID48 Table 81 Dilution factors for the quantification of solvents by GC-MS and GC-FID49 Table 82 Typical retention times for solvents using the polar column (ZB-WAX
43、)49 Table 83 Typical retention times for solvents using the non-polar column (ZB-1)51 Table 84 Typical retention times for certain solvents analysed by GC-MS52 Table 85 Reagents54 Table 86 Reagents55 Table 87 Substances used for the identification and determination of film forming agents56 Table 88
44、Reagents56 Table 89 Mass numbers of the different substances for the SIM-modus58 Table 90 Calibration solutions substances 1 to 9 of Table 8759 Table 91 Calibration solutions Luwax E59 Table B.1 Solvent content in different matrices and permitted maximum concentration62 Table C.1 Content of elements
45、63 Table ZA.1 Correspondence between this European Standard and EU Directives65 BS EN 71-5:1993 BSI 20065 Introduction This European Standard for safety of toys consists of the following Parts: Part 1: Mechanical and physical properties; Part 2: Flammability; Part 3: Migration of certain elements; P
46、art 4: Experimental sets for chemistry and related activities; Part 5: Chemical toys (sets) other than experimental sets; ! Part 6: Graphical symbol for age warning labelling; Part 7: Finger paints Requirements and test methods; Part 8: Swings, slides and similar activity toys for indoor and outdoor
47、 family domestic use; Part 9: Organic chemical compounds Requirements; Part 10: Organic chemical compounds Sample preparation and extraction; Part 11: Organic chemical compounds Methods of analysis.“ This standard is Part 5 of the European Standard for safety of toys, EN 71. This Part should be read
48、 in conjunction with Parts 1, 2 and 3, particularly the introduction and clause 1 of Part 1. It is intended to reduce the risks which may present health hazards to a child when the chemical toys are used as intended or in a foreseeable way, bearing in mind the normal behaviour of children. When using these chemical toys, potential risks should be kept to a minimum by inclusion of appropriate information to give special attention to possible hazards, risks and other p