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1、A Reference number ISO 14910-1:1997(E) INTERNATIONAL STANDARD ISO 14910-1 First edition 1997-12-15 Plastics Thermoplastic polyester/ester and polyether/ester elastomers for moulding and extrusion Part 1: Designation system and basis for specifications Plastiques lastomres thermoplastiques base de po
2、lyester/ester et polyther/ester, pour moulage et extrusion Partie 1: Systme de dsignation et base de spcification ISO 14910-1:1997(E) ISO 1997 All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized in any form or by any means, electronic or mechani
3、cal, including photocopying and microfilm, without permission in writing from the publisher. International Organization for Standardization Case postale 56 CH-1211 Genve 20 Switzerland Internetcentraliso.ch X.400c=ch; a=400net; p=iso; o=isocs; s=central Printed in Switzerland ii Foreword ISO (the In
4、ternational Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee h
5、as been established has the right to be represented on that committee. International organizations, governmental and non- governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnica
6、l standardization. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by at least 75 % of the member bodies casting a vote. International Standard ISO 14910-1 was prepared by Tec
7、hnical Committee ISO/TC 61, Plastics, Subcommittee SC 9, Thermoplastic materials. ISO 14910 consists of the following parts, under the general title Plastics Thermoplastic polyester/ester and polyether/ester elastomers for moulding and extrusion : Part 1: Designation system and basis for specificati
8、ons Part 2: Preparation of test specimens and determination of properties Annex A forms an integral part of this part of ISO 14910. -,-,- INTERNATIONAL STANDARD ISOISO 14910-1:1997(E) 1 Plastics Thermoplastic polyester/ester and polyether/ester elastomers for moulding and extrusion Part 1: Designati
9、on system and basis for specifications 1 Scope 1.1 This part of ISO 14910 establishes a system of designation for thermoplastic polyester/ester and polyether/ester elastomers, which may be used as the basis for specifications. 1.2 The types of thermoplastic polyester/ester and polyether/ester elasto
10、mer are differentiated from each other by a classification system based on appropriate levels of the designatory properties a)hardness; b)melting temperature; c)tensile/flexural modulus of elasticity; and on information about the intended application and/or method of processing, important properties
11、, additives, colourants, fillers and reinforcing materials. 1.3 This part of ISO 14910 is applicable to all thermoplastic polyester/ester and polyether/ester elastomers. It applies to materials ready for normal use in the form of powder, granules or pellets, unmodified or modified by colourants, fil
12、lers or other additives. 1.4 It is not intended to imply that materials having the same designation give necessarily the same performance. This part of ISO 14910 does not provide engineering data, performance data or data on processing conditions which may be required to specify a material for a par
13、ticular application and/or method of processing. If such additional properties are required, they shall be determined in accordance with the test methods specified in part 2 of this International Standard, if suitable. 1.5 In order to specify a thermoplastic polyester/ester or polyether/ester materi
14、al for a particular application or to ensure reproducible processing, additional requirements may be given in data block 5 (see clause 3, introductory paragraph). 2 Normative references The following standards contain provisions which, through reference in this text, constitute provisions of this pa
15、rt of ISO 14910. At the time of publication, the editions indicated were valid. All standards are subject to revision, and parties to agreements based on this part of ISO 14910 are encouraged to investigate the possibility of applying the most recent editions of the standards indicated below. Member
16、s of IEC and ISO maintain registers of currently valid International Standards. ISO 1043-1:1997, Plastics Symbols and abbreviated terms Part 1: Basic polymers and their special characteristics. -,-,- ISO 14910-1:1997(E) ISO 2 ISO 1043-2:1988, Plastics Symbols Part 2: Fillers and reinforcing material
17、s. ISO 14910-2:1997, Plastics Thermoplastic polyester/ester and polyether/ester elastomers for moulding and extrusion Part 2: Preparation of test specimens and determination of properties. 3 Designation system The designation system for thermoplastics is based on the following standardized pattern:
18、Designation Identity block DescriptionInternationalIndividual-item block blockStandardDataDataDataDataData (optional)numberblockblockblockblockblock block12345 The designation consists of an optional description block, reading “Thermoplastics”, and an identity block comprising the International Stan
19、dard number and an individual-item block. For unambiguous designation, the individual-item block is subdivided into 5 data blocks comprising the following information: Data block 1:Identification of the plastic by its symbol in accordance with ISO 1043-1 (see 3.1). Data block 2:Position 1: Intended
20、application or method of processing (see 3.2). Positions 2 to 8: Important properties, additives and supplementary information (see 3.2). Data block 3:Designatory properties (see 3.3). Data block 4:Fillers or reinforcing materials and their nominal content (see 3.4). Data block 5:Information require
21、d for specification purposes is listed here. The use of data block 5 converts the designation to a specification. Only information listed in data block 5 becomes part of the specification requirements. The first character of the individual-item block shall be a hyphen. The data blocks shall be separ
22、ated from each other by commas. If a data block is not used, this shall be indicated by doubling the separation sign, i.e. by two commas (,). 3.1 Data block 1 In this data block, after the hyphen, thermoplastic polyester/ester and polyether/ester elastomers are identified using the symbols and desig
23、nations given in table 1 or developed from annex A. Table 1 Symbols indicating the chemical structure of copolyester/ester and copolyether/ester materials in data block 1 (examples) SymbolChemical identification TP 4T/PTMEGTCopolyether/ester based on butanediol, poly(tetramethylene ether) glycol and
24、 terephthalic acid. TP CL/4TCopolyester/ester based on caprolactone, butanediol and terephthalic acid. TP 4T/PPEGTCopolyether/ester based on butanediol, poly(propylene ether) glycol and terephthalic acid. TP 4T/BDT/PTMEGTCopolyether/ester based on butanediol, butenediol, poly(tetramethylene ether) g
25、lycol and terephthalic acid. -,-,- ISO ISO 14910-1:1997(E) 3 3.2 Data block 2 In this data block, information about intended application and/or method of processing is given in position 1 and information about important properties, additives and colour in positions 2 to 8. The code-letters used are
26、specified in table 2. If information is presented in positions 2 to 8 and no specific information is given in position 1, the letter X shall be inserted in position 1. Table 2 Code-letters used in data block 2 Code- letter Position 1 Code- letter Positions 2 to 8 AAdhesiveAProcessing stabilized BBlo
27、w mouldingBAntiblocking CCalenderingCColoured DDisc manufactureDPowder EExtrusionEExpandable FExtrusion of filmsFSpecial burning characteristics GGeneral useGGranules HCoatingHHeat-ageing stabilized KCable and wire coatingLLight and weather stabilized LMonofilament extrusionMNucleated MMouldingNNatu
28、ral (no colour added) RRotational mouldingPImpact modified SSinteringRMould release agent XNo indicationSLubricated TTransparent WStabilized against hydrolysis ZAntistatic 3.3 Data block 3 In this data block, the hardness is represented by a 2-figure code-number (see 3.3.1), the melting temperature
29、by a 2-figure code-number (see 3.3.2) and the tensile/flexural modulus of elasticity by a 3-figure code-number (see 3.3.3). The code-numbers are separated from each other by hyphens. If a property value falls on or near a range limit, the manufacturer shall state which range will designate the mater
30、ial. If subsequent individual test values lie on, or on either side of, the limit because of manufacturing tolerances, the designation is not affected. NOTE Not all combinations of the values of the designatory properties are provided by currently available polymers. 3.3.1 Hardness The hardness shal
31、l be determined in accordance with ISO 14910-2. The possible values of the hardness are divided into 11 ranges, each represented by a 2-figure code-number as specified in table 3. -,-,- ISO 14910-1:1997(E) ISO 4 Table 3 Code-numbers used for hardness in data block 3 Code-numberRange of hardness 30 3
32、2 but 32 35 32 but 37 40 37 but 42 45 42 but 47 50 47 but 52 55 52 but 57 60 57 but 62 65 62 but 67 70 67 but 72 75 72 but 77 80 77 but 37 3.3.2 Melting temperature The melting temperature shall be determined in accordance with ISO 14910-2. The possible values of the melting temperature are divided
33、into 10 ranges, each represented by a 2-figure code- number as specified in table 4. Table 4 Code-numbers used for melting temperature in data block 3 Code-number Range of melting temperature C 14 145 but 145 15 145 but 155 16 155 but 165 17 165 but 175 18 175 but 185 19 185 but 195 20 195 but 205 2
34、1 205 but 215 22 215 but 225 23 225 but 225 3.3.3 Tensile/flexural modulus of elasticity The tensile/flexural modulus of elasticity shall be determined in accordance with ISO 14910-2. The possible values of the tensile/flexural modulus of elasticity are divided into 10 ranges, each represented by a
35、3-figure code-number as specified in table 5. -,-,- ISO ISO 14910-1:1997(E) 5 Table 5 Code-numbers used for tensile/flexural modulus of elasticity in data block 3 Code-number Range of modulus MPa 002 30 004 30 but 50 006 50 but 70 008 70 but 90 010 90 but 110 015 110 but 200 025 200 but 300 040 300
36、but 500 075 500 but 1 000 100 1 000 3.4 Data block 4 In this data block, the type of filler and/or reinforcing material is represented by a single code-letter in position 1 and its physical form by a second code-letter in position 2, the code-letters being as specified in table 6. Subsequently (with
37、out a space), the mass content may be given by a 2-figure number in positions 3 and 4. Mixtures of materials and/or forms may be indicated by combining the relevant codes using the sign “+” and placing the whole between parentheses. For example, a mixture of 25 % glass fibres (GF) and 10 % mineral p
38、owder (MD) would be indicated by (GF25+MD10). Table 6 Code-letters for fillers and reinforcing materials in data block 4 Code- letter Material Code- letter Form BBoronBBeads, spheres, balls CCarbon 1)DPowder GGlassFFibre KCalcium carbonateGGround MMineral, metal 2)HWhiskers SSynthetic, organic 1)XNo
39、t specified TTalcZOthers XNot specified ZOthers 1) 1) These materials may be further defined by their chemical symbol, for example, or additional symbols defined in the relevant International Standard, or by additional codes to be agreed upon. 2) Metal fillers shall be identified by their chemical s
40、ymbol after the mass content. 3.5 Data block 5 Indication of additional requirements in this optional data block is a way of transforming the designation of a material into a specification for a particular application. This may be done for example by reference to a suitable national standard or to a
41、 standard-like, generally established specification. -,-,- ISO 14910-1:1997(E) ISO 6 4 Examples of designations A thermoplastic copolyether/ester (TP) based on butanediol (4)/terephthalic acid (T) and poly(tetramethylene ether) glycol (PTMEG)/terephthalic acid (T), intended for moulding (M), natural
42、 (not coloured) (N) and having a hardness of 35 (35), a melting temperature of 156 C (16) and a tensile modulus of elasticity of 32 MPa (004), would be designated: Designation: Thermoplastics ISO 14910-TP 4T/PTMEGT,MN,35-16-004 A thermoplastic copolyester/ester (TP) based on butanediol (4)/terephtha
43、lic acid (T) and caprolactone (CL), intended for moulding (M), natural (not coloured) (N), stabilized for heat-ageing (H) and having a hardness of 48 (50), a melting temperature of 200 C (20) and a tensile modulus of elasticity of 127 MPa (015), would be designated: Designation: Thermoplastics ISO 1
44、4910-TP 4T/CL,MNH,50-20-015 -,-,- ISO ISO 14910-1:1997(E) 7 Annex A (normative) Designation of thermoplastic polyester/ester and polyether/ester copolymer elastomers Thermoplastic polyester materials contain ester groups, -CO-O-, at regular intervals in the linear polymer chain. One segment of a pol
45、yester/ester copolymer is built up from a starting material with hydroxyl (-OH) groups, also called diols, plus a starting material with carboxylic acid (-COOH) groups, also called dicarboxylic acids, or esters of such acids, and the second segment is built up from a hydroxycarboxylic acid or its la
46、ctone, in each case by a polycondensation process. One segment of a polyether/ester copolymer is built up from diols and dicarboxylic acids, or esters of such acids, and the second segment is built up from polyalkylene ether glycols and dicarboxylic acids, in each case by a polycondensation process.
47、 Aliphatic polyester segments based on linear diols and linear dicarboxylic acids or esters of such acids are designated by two or more code-numbers. The first code-number (which may have one or two digits) corresponds to the number of C-atoms in the linear diol (see table A.1) and the second code-n
48、umber (which may also have one or two digits) corresponds to the number of C-atoms in the linear dicarboxylic acid (see table A.2). Non-linear aliphatic, cycloaliphatic and aromatic compounds used as monomer units in the polyester chain are designated by code-letters (see tables A.1, A.2 and A.3). Copolyesters are designated by an oblique stroke (/) between the code-numbers representing the components of the copolyester (cf annex A, clause A.6, in ISO 104